TY - JOUR
T1 - 2-[(4-tert-Butyl-anilino)(phen-yl)meth-yl]cyclo-hexa-none
AU - Fun, Hoong Kun
AU - Chantrapromma, Suchada
AU - Rai, Sankappa
AU - Shetty, Prakash
AU - Isloor, Arun M.
PY - 2009/3/18
Y1 - 2009/3/18
N2 - In the mol-ecule of the title compound, C23H29NO, the cyclo-hexa-none ring has been distorted from the standard chair conformation by the ketone group such that part of the ring is almost flat. The remaining [(4-tert-butyl-anilino)(phen-yl)meth-yl] portion of the mol-ecule is in an equatorial position on the cyclo-hexa-none ring. The dihedral angle between the two benzene rings is 81.52 (8)°. In the crystal packing, mol-ecules are linked by N - H⋯O hydrogen bonds into infinite one-dimensional chains along the a axis and these chains are stacked down the c axis. The crystal structure is further stabilized by weak C - H⋯O and C - H⋯π inter-actions.
AB - In the mol-ecule of the title compound, C23H29NO, the cyclo-hexa-none ring has been distorted from the standard chair conformation by the ketone group such that part of the ring is almost flat. The remaining [(4-tert-butyl-anilino)(phen-yl)meth-yl] portion of the mol-ecule is in an equatorial position on the cyclo-hexa-none ring. The dihedral angle between the two benzene rings is 81.52 (8)°. In the crystal packing, mol-ecules are linked by N - H⋯O hydrogen bonds into infinite one-dimensional chains along the a axis and these chains are stacked down the c axis. The crystal structure is further stabilized by weak C - H⋯O and C - H⋯π inter-actions.
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U2 - 10.1107/S1600536809004954
DO - 10.1107/S1600536809004954
M3 - Article
AN - SCOPUS:62149127030
SN - 1600-5368
VL - 65
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 3
ER -