2-Chloro-4-nitro-1H-imidazole

Hoong Kun Fun; Jia Hao Goh; B. Chandrakantha; Arun M. Isloor; Prakash Shetty

doi:10.1107/S1600536810024542

2-Chloro-4-nitro-1H-imidazole

Hoong Kun Fun, Jia Hao Goh, B. Chandrakantha, Arun M. Isloor, Prakash Shetty

Department of Chemistry, Manipal Institute of Technology, Manipal

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

The molecule of the title compound, C₃H₂ClN ₃O₂, is almost planar; the dihedral angle between the imidazole ring and the nitro group is 1.7 (2)°. In the crystal structure, pairs of inter-molecular C-H⋯O hydrogen bonds link inversion-related molecules into dimers, generating R₂ ²(10) ring motifs. The dimers are inter-connected into two-dimensional networks parallel to (102) via inter-molecular N-H⋯N hydrogen bonds. Further stabilization is provided by short inter-molecular Cl⋯O inter-actions [3.142 (2) and 3.1475 (19) Å].

Original language	English
Pages (from-to)	o1828-o1829
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	66
Issue number	7
DOIs	https://doi.org/10.1107/S1600536810024542
Publication status	Published - 14-07-2010

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

Access to Document

10.1107/S1600536810024542

Cite this

@article{dbe6d2ac3d304ce5952709be0ea53610,

title = "2-Chloro-4-nitro-1H-imidazole",

abstract = "The molecule of the title compound, C3H2ClN 3O2, is almost planar; the dihedral angle between the imidazole ring and the nitro group is 1.7 (2)°. In the crystal structure, pairs of inter-molecular C-H⋯O hydrogen bonds link inversion-related molecules into dimers, generating R2 2(10) ring motifs. The dimers are inter-connected into two-dimensional networks parallel to (102) via inter-molecular N-H⋯N hydrogen bonds. Further stabilization is provided by short inter-molecular Cl⋯O inter-actions [3.142 (2) and 3.1475 (19) {\AA}].",

author = "Fun, {Hoong Kun} and Goh, {Jia Hao} and B. Chandrakantha and Isloor, {Arun M.} and Prakash Shetty",

year = "2010",

month = jul,

day = "14",

doi = "10.1107/S1600536810024542",

language = "English",

volume = "66",

pages = "o1828--o1829",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "7",

}

TY - JOUR

T1 - 2-Chloro-4-nitro-1H-imidazole

AU - Fun, Hoong Kun

AU - Goh, Jia Hao

AU - Chandrakantha, B.

AU - Isloor, Arun M.

AU - Shetty, Prakash

PY - 2010/7/14

Y1 - 2010/7/14

N2 - The molecule of the title compound, C3H2ClN 3O2, is almost planar; the dihedral angle between the imidazole ring and the nitro group is 1.7 (2)°. In the crystal structure, pairs of inter-molecular C-H⋯O hydrogen bonds link inversion-related molecules into dimers, generating R2 2(10) ring motifs. The dimers are inter-connected into two-dimensional networks parallel to (102) via inter-molecular N-H⋯N hydrogen bonds. Further stabilization is provided by short inter-molecular Cl⋯O inter-actions [3.142 (2) and 3.1475 (19) Å].

AB - The molecule of the title compound, C3H2ClN 3O2, is almost planar; the dihedral angle between the imidazole ring and the nitro group is 1.7 (2)°. In the crystal structure, pairs of inter-molecular C-H⋯O hydrogen bonds link inversion-related molecules into dimers, generating R2 2(10) ring motifs. The dimers are inter-connected into two-dimensional networks parallel to (102) via inter-molecular N-H⋯N hydrogen bonds. Further stabilization is provided by short inter-molecular Cl⋯O inter-actions [3.142 (2) and 3.1475 (19) Å].

UR - http://www.scopus.com/inward/record.url?scp=77954419872&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=77954419872&partnerID=8YFLogxK

U2 - 10.1107/S1600536810024542

DO - 10.1107/S1600536810024542

M3 - Article

AN - SCOPUS:77954419872

SN - 1600-5368

VL - 66

SP - o1828-o1829

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 7

ER -

2-Chloro-4-nitro-1H-imidazole

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this