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2-Methyl-5-[(3-methyl-4-nitrobenzyl)-sulfanyl]-1,3,4-thiadiazole

  • Hoong Kun Fun*
  • , Suchada Chantrapromma
  • , B. Chandrakantha
  • , Arun M. Isloor
  • , Prakash Shetty
  • *Corresponding author for this work

    Research output: Contribution to journalArticlepeer-review

    Abstract

    The molecule of the title thiadiazole derivative, C11H 11N3O2S2, has a butterfly-like structure and the whole molecule is disordered with a site-occupancy ratio of 0.629 (4):0.371 (4). The molecule is disordered in such a way that the 3-methyl-4-nitrophenyl units of the major and minor components are approximately related by 180° rotation around the C - N bond axis. The dihedral angle between the 1,3,4-thiadiazole and benzene rings is 70.8 (4) ° in the major component and 74.9 (6) ° in the minor component. In the crystal, molecules are arranged into screw chains along the c axis. These chains are stacked along the b axis. Weak intermolecular C - H⋯O and C - H⋯π interactions and a short C⋯O contact [3.005 (7) Å] are present.

    Original languageEnglish
    Pages (from-to)o205-o206
    JournalActa Crystallographica Section E: Structure Reports Online
    Volume67
    Issue number1
    DOIs
    Publication statusPublished - 01-01-2011

    All Science Journal Classification (ASJC) codes

    • Condensed Matter Physics
    • General Materials Science
    • General Chemistry

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