A new method for the generation of α-nitrosoolefins from ketooximes and its application to the synthesis of 5,6-dihydro-4H-1,2-oxazine derivatives [1]

S. L. Gaonkar; K. M.Lokanatha Rai

doi:10.1002/jhet.5570420520

A new method for the generation of α-nitrosoolefins from ketooximes and its application to the synthesis of 5,6-dihydro-4H-1,2-oxazine derivatives [1]

S. L. Gaonkar
, K. M.Lokanatha Rai^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

Reaction of ketooximes containing α-methylene group with chloramine-T followed by treatment with triethylamine leads to the formation of α-nitrosoolefins via α-nitrosochloride, which can react in situ intermolecularly with olefinic compounds to produce 5,6-dihydro-4H-1,2-oxazine derivatives in good yield.

Original language	English
Pages (from-to)	877-881
Number of pages	5
Journal	Journal of Heterocyclic Chemistry
Volume	42
Issue number	5
DOIs	https://doi.org/10.1002/jhet.5570420520
Publication status	Published - 07-2005

All Science Journal Classification (ASJC) codes

Organic Chemistry

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10.1002/jhet.5570420520

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abstract = "Reaction of ketooximes containing α-methylene group with chloramine-T followed by treatment with triethylamine leads to the formation of α-nitrosoolefins via α-nitrosochloride, which can react in situ intermolecularly with olefinic compounds to produce 5,6-dihydro-4H-1,2-oxazine derivatives in good yield.",

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AU - Gaonkar, S. L.

AU - Rai, K. M.Lokanatha

PY - 2005/7

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N2 - Reaction of ketooximes containing α-methylene group with chloramine-T followed by treatment with triethylamine leads to the formation of α-nitrosoolefins via α-nitrosochloride, which can react in situ intermolecularly with olefinic compounds to produce 5,6-dihydro-4H-1,2-oxazine derivatives in good yield.

AB - Reaction of ketooximes containing α-methylene group with chloramine-T followed by treatment with triethylamine leads to the formation of α-nitrosoolefins via α-nitrosochloride, which can react in situ intermolecularly with olefinic compounds to produce 5,6-dihydro-4H-1,2-oxazine derivatives in good yield.

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SN - 0022-152X

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JO - Journal of Heterocyclic Chemistry

JF - Journal of Heterocyclic Chemistry

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ER -

A new method for the generation of α-nitrosoolefins from ketooximes and its application to the synthesis of 5,6-dihydro-4H-1,2-oxazine derivatives [1]

Abstract

All Science Journal Classification (ASJC) codes

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