A review on current trends in potential use of metal-organic framework for hydrogen storage

Sachin P. Shet; S. Shanmuga Priya; K. Sudhakar; Muhammad Tahir

doi:10.1016/j.ijhydene.2021.01.020

A review on current trends in potential use of metal-organic framework for hydrogen storage

Sachin P. Shet
, S. Shanmuga Priya^*
, K. Sudhakar
, Muhammad Tahir

^*Corresponding author for this work

Research output: Contribution to journal › Review article › peer-review

402 Citations (Scopus)

Abstract

Hydrogen can be a promising clean energy carrier for the replenishment of non-renewable fossil fuels. The set back of hydrogen as an alternative fuel is due to its difficulties in feasible storage and safety concerns. Current hydrogen adsorption technologies, such as cryo-compressed and liquefied storage, are costly for practical applications. Metal-organic frameworks (MOFs) are crystalline materials that have structural versatility, high porosity and surface area, which can adsorb hydrogen efficiently. Hydrogen is adsorbed by physisorption on the MOFs through weak van der Waals force of attraction which can be easily desorbed by applying suitable heat or pressure. The strategies to improve the MOFs surface area, hydrogen uptake capacities and parameters affecting them are studied. Hydrogen spill over mechanism is found to provide high-density storage when compared to other mechanisms. MOFs can be used as proton exchange membranes to convert the stored hydrogen into electricity and can be used as electrodes for the fuel cells. In this review, we addressed the key strategies that could improve hydrogen storage properties for utilizing hydrogen as fuel and opportunities for further growth to meet energy demands.

Original language	English
Pages (from-to)	11782-11803
Number of pages	22
Journal	International Journal of Hydrogen Energy
Volume	46
Issue number	21
DOIs	https://doi.org/10.1016/j.ijhydene.2021.01.020
Publication status	Published - 23-03-2021

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

All Science Journal Classification (ASJC) codes

Renewable Energy, Sustainability and the Environment
Fuel Technology
Condensed Matter Physics
Energy Engineering and Power Technology

Access to Document

10.1016/j.ijhydene.2021.01.020

Cite this

@article{f6430a52b0a44250b8a7fbbe59991171,

title = "A review on current trends in potential use of metal-organic framework for hydrogen storage",

abstract = "Hydrogen can be a promising clean energy carrier for the replenishment of non-renewable fossil fuels. The set back of hydrogen as an alternative fuel is due to its difficulties in feasible storage and safety concerns. Current hydrogen adsorption technologies, such as cryo-compressed and liquefied storage, are costly for practical applications. Metal-organic frameworks (MOFs) are crystalline materials that have structural versatility, high porosity and surface area, which can adsorb hydrogen efficiently. Hydrogen is adsorbed by physisorption on the MOFs through weak van der Waals force of attraction which can be easily desorbed by applying suitable heat or pressure. The strategies to improve the MOFs surface area, hydrogen uptake capacities and parameters affecting them are studied. Hydrogen spill over mechanism is found to provide high-density storage when compared to other mechanisms. MOFs can be used as proton exchange membranes to convert the stored hydrogen into electricity and can be used as electrodes for the fuel cells. In this review, we addressed the key strategies that could improve hydrogen storage properties for utilizing hydrogen as fuel and opportunities for further growth to meet energy demands.",

author = "Shet, \{Sachin P.\} and \{Shanmuga Priya\}, S. and K. Sudhakar and Muhammad Tahir",

note = "Funding Information: The authors would like to acknowledge the Manipal Academy of Higher Education, Manipal, India for the grant of research seed money for a project titled “Carbon capture and conversion to methanol using metal-organic framework as an adsorbent material” (Grant ID: 00000191/2019 ) and Vision Group of Science and Technology (VGST) , Department of Science and Technology (DST) , Government of Karnataka, India for the project grant titled “Photocatalytic conversion of carbon dioxide to methanol using ZIF-8/BiVO4/GO and rGO/CuO nanocomposites as an adsorbent material” (2020) (Ref No: VGST/RGS-F/GRD-918/2019–20/2020-21/198 ). Publisher Copyright: {\textcopyright} 2021 Hydrogen Energy Publications LLC Copyright: Copyright 2021 Elsevier B.V., All rights reserved.",

year = "2021",

month = mar,

day = "23",

doi = "10.1016/j.ijhydene.2021.01.020",

language = "English",

volume = "46",

pages = "11782--11803",

journal = "International Journal of Hydrogen Energy",

issn = "0360-3199",

publisher = "Elsevier Ltd",

number = "21",

}

TY - JOUR

T1 - A review on current trends in potential use of metal-organic framework for hydrogen storage

AU - Shet, Sachin P.

AU - Shanmuga Priya, S.

AU - Sudhakar, K.

AU - Tahir, Muhammad

N1 - Funding Information: The authors would like to acknowledge the Manipal Academy of Higher Education, Manipal, India for the grant of research seed money for a project titled “Carbon capture and conversion to methanol using metal-organic framework as an adsorbent material” (Grant ID: 00000191/2019 ) and Vision Group of Science and Technology (VGST) , Department of Science and Technology (DST) , Government of Karnataka, India for the project grant titled “Photocatalytic conversion of carbon dioxide to methanol using ZIF-8/BiVO4/GO and rGO/CuO nanocomposites as an adsorbent material” (2020) (Ref No: VGST/RGS-F/GRD-918/2019–20/2020-21/198 ). Publisher Copyright: © 2021 Hydrogen Energy Publications LLC Copyright: Copyright 2021 Elsevier B.V., All rights reserved.

PY - 2021/3/23

Y1 - 2021/3/23

N2 - Hydrogen can be a promising clean energy carrier for the replenishment of non-renewable fossil fuels. The set back of hydrogen as an alternative fuel is due to its difficulties in feasible storage and safety concerns. Current hydrogen adsorption technologies, such as cryo-compressed and liquefied storage, are costly for practical applications. Metal-organic frameworks (MOFs) are crystalline materials that have structural versatility, high porosity and surface area, which can adsorb hydrogen efficiently. Hydrogen is adsorbed by physisorption on the MOFs through weak van der Waals force of attraction which can be easily desorbed by applying suitable heat or pressure. The strategies to improve the MOFs surface area, hydrogen uptake capacities and parameters affecting them are studied. Hydrogen spill over mechanism is found to provide high-density storage when compared to other mechanisms. MOFs can be used as proton exchange membranes to convert the stored hydrogen into electricity and can be used as electrodes for the fuel cells. In this review, we addressed the key strategies that could improve hydrogen storage properties for utilizing hydrogen as fuel and opportunities for further growth to meet energy demands.

AB - Hydrogen can be a promising clean energy carrier for the replenishment of non-renewable fossil fuels. The set back of hydrogen as an alternative fuel is due to its difficulties in feasible storage and safety concerns. Current hydrogen adsorption technologies, such as cryo-compressed and liquefied storage, are costly for practical applications. Metal-organic frameworks (MOFs) are crystalline materials that have structural versatility, high porosity and surface area, which can adsorb hydrogen efficiently. Hydrogen is adsorbed by physisorption on the MOFs through weak van der Waals force of attraction which can be easily desorbed by applying suitable heat or pressure. The strategies to improve the MOFs surface area, hydrogen uptake capacities and parameters affecting them are studied. Hydrogen spill over mechanism is found to provide high-density storage when compared to other mechanisms. MOFs can be used as proton exchange membranes to convert the stored hydrogen into electricity and can be used as electrodes for the fuel cells. In this review, we addressed the key strategies that could improve hydrogen storage properties for utilizing hydrogen as fuel and opportunities for further growth to meet energy demands.

UR - https://www.scopus.com/pages/publications/85100579071

UR - https://www.scopus.com/pages/publications/85100579071#tab=citedBy

U2 - 10.1016/j.ijhydene.2021.01.020

DO - 10.1016/j.ijhydene.2021.01.020

M3 - Review article

AN - SCOPUS:85100579071

SN - 0360-3199

VL - 46

SP - 11782

EP - 11803

JO - International Journal of Hydrogen Energy

JF - International Journal of Hydrogen Energy

IS - 21

ER -

A review on current trends in potential use of metal-organic framework for hydrogen storage

Abstract

UN SDGs

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this