A zinc-quinone battery for paired hydrogen peroxide electrosynthesis

Hydrogen peroxide is a commodity chemical with immense applications as an environmentally benign disinfectant for water remediation, a green oxidant for synthetic chemistry and pulp bleaching, an energy carrier molecule and a rocket propellant. It is typically synthesized by indirect batch anthraquinone process, where sequential hydrogenation and oxidation of anthraquinone molecules generates H₂O₂. This highly energy demanding catalytic sequence necessitates the advent of new reaction pathways with lower energy expenditure. Here we demonstrate a Zn-quinone battery for paired H₂O₂ electrosynthesis at the three phase boundary of its cathodic half-cell during electric power generation. The catalytic quinone half-cell of the Zn-quinone battery, mediates proton coupled electron transfer with molecular oxygen during its chemical regeneration thereby pairing peroxide electrosynthesis with electricity generation. Hydrogen peroxide synthesizing Zn-quinone battery (HPSB) demonstrated a peak power density of ~90 mW/cm² at a peak current density of ~145 mA/cm² while synthesizing ~230 mM of H₂O₂. HPSB offers immense opportunities as it distinctly couples electric power generation with peroxide electrosynthesis which in-turn transforms energy conversion in batteries truly multifunctional.