Catena-Poly[[(ethanol-O)[3-(1-phenyl-1H-pyrazol-3-yl)benzoic acid-O]lithium] - 3-(1-phenyl-1H-pyrazol-3-yl)benzoato-2 O: O′]

Hoong Kun Fun; Kasthuri Balasubramani; Sankappa Rai; Prakash Shetty; Arun M. Isloor

doi:10.1107/S1600536809026385

Catena-Poly[[(ethanol-O)[3-(1-phenyl-1H-pyrazol-3-yl)benzoic acid-O]lithium] - 3-(1-phenyl-1H-pyrazol-3-yl)benzoato-² O: O′]

Hoong Kun Fun, Kasthuri Balasubramani, Sankappa Rai, Prakash Shetty, Arun M. Isloor

Department of Chemistry, Manipal Institute of Technology, Manipal

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The asymmetric unit of the title polymeric compound, [Li₂(C ₁₆H₁₁N₂O₂)₂(C ₁₆H₁₂N₂O₂)₂(CH ₃CH₂OH)₂] _n , contains two Li ^I ions, two 3-(1-phenyl-1H-pyrazol-3-yl)benzoate ions, two 3-(1-phenyl-1H-pyrazol-3-yl)benzoic acid molecules and two ethanol molecules. In the crystal structure, each of the two Li^I ions has a distorted tetra-hedral geometry, coordinated by two carboxyl-ate O atoms, one carboxyl O atom and one ethanol O atom. The carboxyl-ate group bridges the Li^I ions, forming a one-dimensional polymeric chain along [100]. The crystal structure is further stabilized by O - H⋯O and C - H⋯N hydrogen bonding, and π-π inter-actions with centroid-centroid distances in the range 3.6534 (13)-3.8374 (13) Å.

Original language	English
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	65
Issue number	8
DOIs	https://doi.org/10.1107/S1600536809026385
Publication status	Published - 20-08-2009

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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@article{98e59e05210c4c1f8e2ebfaa05a53c9e,

title = "Catena-Poly[[(ethanol-O)[3-(1-phenyl-1H-pyrazol-3-yl)benzoic acid-O]lithium] - 3-(1-phenyl-1H-pyrazol-3-yl)benzoato-2 O: O′]",

abstract = "The asymmetric unit of the title polymeric compound, [Li2(C 16H11N2O2)2(C 16H12N2O2)2(CH 3CH2OH)2] n , contains two Li I ions, two 3-(1-phenyl-1H-pyrazol-3-yl)benzoate ions, two 3-(1-phenyl-1H-pyrazol-3-yl)benzoic acid molecules and two ethanol molecules. In the crystal structure, each of the two LiI ions has a distorted tetra-hedral geometry, coordinated by two carboxyl-ate O atoms, one carboxyl O atom and one ethanol O atom. The carboxyl-ate group bridges the LiI ions, forming a one-dimensional polymeric chain along [100]. The crystal structure is further stabilized by O - H⋯O and C - H⋯N hydrogen bonding, and π-π inter-actions with centroid-centroid distances in the range 3.6534 (13)-3.8374 (13) {\AA}.",

author = "Fun, {Hoong Kun} and Kasthuri Balasubramani and Sankappa Rai and Prakash Shetty and Isloor, {Arun M.}",

year = "2009",

month = aug,

day = "20",

doi = "10.1107/S1600536809026385",

language = "English",

volume = "65",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "8",

}

TY - JOUR

T1 - Catena-Poly[[(ethanol-O)[3-(1-phenyl-1H-pyrazol-3-yl)benzoic acid-O]lithium] - 3-(1-phenyl-1H-pyrazol-3-yl)benzoato-2 O

T2 - O′]

AU - Fun, Hoong Kun

AU - Balasubramani, Kasthuri

AU - Rai, Sankappa

AU - Shetty, Prakash

AU - Isloor, Arun M.

PY - 2009/8/20

Y1 - 2009/8/20

N2 - The asymmetric unit of the title polymeric compound, [Li2(C 16H11N2O2)2(C 16H12N2O2)2(CH 3CH2OH)2] n , contains two Li I ions, two 3-(1-phenyl-1H-pyrazol-3-yl)benzoate ions, two 3-(1-phenyl-1H-pyrazol-3-yl)benzoic acid molecules and two ethanol molecules. In the crystal structure, each of the two LiI ions has a distorted tetra-hedral geometry, coordinated by two carboxyl-ate O atoms, one carboxyl O atom and one ethanol O atom. The carboxyl-ate group bridges the LiI ions, forming a one-dimensional polymeric chain along [100]. The crystal structure is further stabilized by O - H⋯O and C - H⋯N hydrogen bonding, and π-π inter-actions with centroid-centroid distances in the range 3.6534 (13)-3.8374 (13) Å.

AB - The asymmetric unit of the title polymeric compound, [Li2(C 16H11N2O2)2(C 16H12N2O2)2(CH 3CH2OH)2] n , contains two Li I ions, two 3-(1-phenyl-1H-pyrazol-3-yl)benzoate ions, two 3-(1-phenyl-1H-pyrazol-3-yl)benzoic acid molecules and two ethanol molecules. In the crystal structure, each of the two LiI ions has a distorted tetra-hedral geometry, coordinated by two carboxyl-ate O atoms, one carboxyl O atom and one ethanol O atom. The carboxyl-ate group bridges the LiI ions, forming a one-dimensional polymeric chain along [100]. The crystal structure is further stabilized by O - H⋯O and C - H⋯N hydrogen bonding, and π-π inter-actions with centroid-centroid distances in the range 3.6534 (13)-3.8374 (13) Å.

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JO - Acta Crystallographica Section E: Structure Reports Online

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Catena-Poly[[(ethanol-O)[3-(1-phenyl-1H-pyrazol-3-yl)benzoic acid-O]lithium] - 3-(1-phenyl-1H-pyrazol-3-yl)benzoato-² O: O′]

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