Design, synthesis and nonlinear optical characterization of novel mixed ligand ruthenium metal-organic complex

K. B. Manjunatha; Dileep Ramakrishna; B. J. Rudresha; Albin Antony; P. Poornesh

doi:10.1016/j.optmat.2020.110068

Design, synthesis and nonlinear optical characterization of novel mixed ligand ruthenium metal-organic complex

K. B. Manjunatha^*
, Dileep Ramakrishna
, B. J. Rudresha
, Albin Antony
, P. Poornesh

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

In the present study, novel mixed ligand ruthenium metal-organic complex (RuThAP) was designed and synthesized. The chemical structural analysis was performed using NMR, UV–Vis and FTIR spectroscopy. RuThAP/Poly(methylmethacrylate) (PMMA) films were successfully fabricated by homogeneously embedding RuThAP in optically inactive PMMA using spin-coating. Third-order nonlinear optical coefficients of RuThAP in liquid and solid phase were determined by Z-scan technique with nanosecond laser beam. RuThAP molecule exhibited strong reverse saturable absorptive (β_eff = 8.81 ± 0.88 x10⁻⁹ m/W) and negative refractive (n₂ = −5.47 ± 0.55 x10⁻⁹ esu) optical nonlinearity at 532 nm. The RuThAP molecule also demonstrated strong optical limitation with optical limiting clamping level as low as 38 μJ due to large absorptive optical nonlinearity. These results pave the platform for high efficient metal-organic/PMMA films based solid-state optical limiters with low cost, flexible, dependable and low optical loss.

Original language	English
Article number	110068
Journal	Optical Materials
Volume	107
DOIs	https://doi.org/10.1016/j.optmat.2020.110068
Publication status	Published - 09-2020

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
General Computer Science
Atomic and Molecular Physics, and Optics
Spectroscopy
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Electrical and Electronic Engineering

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@article{616ddd85ad2b4313935fcae499beaa0d,

title = "Design, synthesis and nonlinear optical characterization of novel mixed ligand ruthenium metal-organic complex",

abstract = "In the present study, novel mixed ligand ruthenium metal-organic complex (RuThAP) was designed and synthesized. The chemical structural analysis was performed using NMR, UV–Vis and FTIR spectroscopy. RuThAP/Poly(methylmethacrylate) (PMMA) films were successfully fabricated by homogeneously embedding RuThAP in optically inactive PMMA using spin-coating. Third-order nonlinear optical coefficients of RuThAP in liquid and solid phase were determined by Z-scan technique with nanosecond laser beam. RuThAP molecule exhibited strong reverse saturable absorptive (βeff = 8.81 ± 0.88 x10−9 m/W) and negative refractive (n2 = −5.47 ± 0.55 x10−9 esu) optical nonlinearity at 532 nm. The RuThAP molecule also demonstrated strong optical limitation with optical limiting clamping level as low as 38 μJ due to large absorptive optical nonlinearity. These results pave the platform for high efficient metal-organic/PMMA films based solid-state optical limiters with low cost, flexible, dependable and low optical loss.",

author = "Manjunatha, \{K. B.\} and Dileep Ramakrishna and Rudresha, \{B. J.\} and Albin Antony and P. Poornesh",

note = "Publisher Copyright: {\textcopyright} 2020 Elsevier B.V.",

year = "2020",

month = sep,

doi = "10.1016/j.optmat.2020.110068",

language = "English",

volume = "107",

journal = "Optical Materials",

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T1 - Design, synthesis and nonlinear optical characterization of novel mixed ligand ruthenium metal-organic complex

AU - Manjunatha, K. B.

AU - Ramakrishna, Dileep

AU - Rudresha, B. J.

AU - Antony, Albin

AU - Poornesh, P.

PY - 2020/9

Y1 - 2020/9

N2 - In the present study, novel mixed ligand ruthenium metal-organic complex (RuThAP) was designed and synthesized. The chemical structural analysis was performed using NMR, UV–Vis and FTIR spectroscopy. RuThAP/Poly(methylmethacrylate) (PMMA) films were successfully fabricated by homogeneously embedding RuThAP in optically inactive PMMA using spin-coating. Third-order nonlinear optical coefficients of RuThAP in liquid and solid phase were determined by Z-scan technique with nanosecond laser beam. RuThAP molecule exhibited strong reverse saturable absorptive (βeff = 8.81 ± 0.88 x10−9 m/W) and negative refractive (n2 = −5.47 ± 0.55 x10−9 esu) optical nonlinearity at 532 nm. The RuThAP molecule also demonstrated strong optical limitation with optical limiting clamping level as low as 38 μJ due to large absorptive optical nonlinearity. These results pave the platform for high efficient metal-organic/PMMA films based solid-state optical limiters with low cost, flexible, dependable and low optical loss.

AB - In the present study, novel mixed ligand ruthenium metal-organic complex (RuThAP) was designed and synthesized. The chemical structural analysis was performed using NMR, UV–Vis and FTIR spectroscopy. RuThAP/Poly(methylmethacrylate) (PMMA) films were successfully fabricated by homogeneously embedding RuThAP in optically inactive PMMA using spin-coating. Third-order nonlinear optical coefficients of RuThAP in liquid and solid phase were determined by Z-scan technique with nanosecond laser beam. RuThAP molecule exhibited strong reverse saturable absorptive (βeff = 8.81 ± 0.88 x10−9 m/W) and negative refractive (n2 = −5.47 ± 0.55 x10−9 esu) optical nonlinearity at 532 nm. The RuThAP molecule also demonstrated strong optical limitation with optical limiting clamping level as low as 38 μJ due to large absorptive optical nonlinearity. These results pave the platform for high efficient metal-organic/PMMA films based solid-state optical limiters with low cost, flexible, dependable and low optical loss.

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UR - https://www.scopus.com/pages/publications/85086801092#tab=citedBy

U2 - 10.1016/j.optmat.2020.110068

DO - 10.1016/j.optmat.2020.110068

M3 - Article

AN - SCOPUS:85086801092

SN - 0925-3467

VL - 107

JO - Optical Materials

JF - Optical Materials

M1 - 110068

ER -

Design, synthesis and nonlinear optical characterization of novel mixed ligand ruthenium metal-organic complex

Abstract

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