TY - JOUR
T1 - Dicyclohexylammonium O,O′-diphenyl phosphate, [(C
6
H
11
)
2
NH
2
][(C
6
H
5
O)
2
P(O)(O)]
T2 - Spectroscopic study, crystal structure, and hirshfeld surface analysis
AU - Moghaddam, Samira Nazari
AU - Shabari, Akbar Raissi
AU - Sabbaghi, Fahimeh
AU - Pourayoubi, Mehrdad
AU - Salam, Abdul Ajees Abdul
PY - 2019/3/1
Y1 - 2019/3/1
N2 -
The title salt, [(C
6
H
11
)
2
NH
2
][(C
6
H
5
O)
2
P(O)(O)], crystallizes in the chiral space group P2
1
2
1
2
1
, composed of achiral cation and anion components. The strong charge-assisted N–H…O hydrogen bonds build a linear assembly along the a axis, including a non-centrosymmetric C
2
2
(6) chain graph-set motif. The intra and intermolecular C–H…O interactions as well as the C–H…π-electron ring interactions also exist in the crystal structure. Fingerprint plots are used for a detailed investigation of intermolecular interactions participating in the crystal packing. The spectroscopic features (IR,
1
H NMR,
13
C{
1
H} NMR,
31
P{
1
H} NMR, and mass) are studied.
AB -
The title salt, [(C
6
H
11
)
2
NH
2
][(C
6
H
5
O)
2
P(O)(O)], crystallizes in the chiral space group P2
1
2
1
2
1
, composed of achiral cation and anion components. The strong charge-assisted N–H…O hydrogen bonds build a linear assembly along the a axis, including a non-centrosymmetric C
2
2
(6) chain graph-set motif. The intra and intermolecular C–H…O interactions as well as the C–H…π-electron ring interactions also exist in the crystal structure. Fingerprint plots are used for a detailed investigation of intermolecular interactions participating in the crystal packing. The spectroscopic features (IR,
1
H NMR,
13
C{
1
H} NMR,
31
P{
1
H} NMR, and mass) are studied.
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U2 - 10.3390/M1051
DO - 10.3390/M1051
M3 - Article
AN - SCOPUS:85064115276
SN - 1422-8599
VL - 2019
JO - MolBank
JF - MolBank
IS - 1
M1 - 1051
ER -