TY - JOUR
T1 - Effect of sintering temperature on the structural, morphological, optical and electrical properties of Ba1 − xLaxFe12O19
AU - Nishkala, K. R.
AU - Rao, Rajat Radhakrishna
AU - Mutalik, Srinivas
AU - Murari, M. S.
AU - Daivajna, Mamatha D.
N1 - Publisher Copyright:
© The Author(s) 2024.
PY - 2024/8
Y1 - 2024/8
N2 - La substituted M-type Barium hexaferrite, Ba(1−x)La(x)Fe12O19, (x = 0.25 and 0.30) were synthesized using ball milling followed by heat treatment at 1150˚C and 1300˚C and the influence of sintering temperature as well as La doping were presented. X-ray diffraction, FESEM, dielectric spectroscopy, and ferroelectric measurements were performed to study the structural, morphological, dielectric, and ferroelectric properties of the prepared samples. Rietveld refinement on the X-ray diffraction measurement reveals the formation of a phase magnetoplumbite structure of barium hexaferrite only for the samples sintered at 1300˚C. The secondary phase, along with the major magnetoplumbite structure, was observed for the sample sintered at 1150˚C. Hexagonal plate-like grains of different sizes were observed, and samples sintered at 1300˚C showed large-size grains. Porosity was observed to decrease with La doping. Impedance spectroscopy reveals that Maxwell-Wagner-type polarisation occurs with the relaxation of mobile charges having long-range hopping. However, the ferroelectric property was suppressed for samples sintered at 1300˚C.
AB - La substituted M-type Barium hexaferrite, Ba(1−x)La(x)Fe12O19, (x = 0.25 and 0.30) were synthesized using ball milling followed by heat treatment at 1150˚C and 1300˚C and the influence of sintering temperature as well as La doping were presented. X-ray diffraction, FESEM, dielectric spectroscopy, and ferroelectric measurements were performed to study the structural, morphological, dielectric, and ferroelectric properties of the prepared samples. Rietveld refinement on the X-ray diffraction measurement reveals the formation of a phase magnetoplumbite structure of barium hexaferrite only for the samples sintered at 1300˚C. The secondary phase, along with the major magnetoplumbite structure, was observed for the sample sintered at 1150˚C. Hexagonal plate-like grains of different sizes were observed, and samples sintered at 1300˚C showed large-size grains. Porosity was observed to decrease with La doping. Impedance spectroscopy reveals that Maxwell-Wagner-type polarisation occurs with the relaxation of mobile charges having long-range hopping. However, the ferroelectric property was suppressed for samples sintered at 1300˚C.
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U2 - 10.1007/s00339-024-07696-0
DO - 10.1007/s00339-024-07696-0
M3 - Article
AN - SCOPUS:85197514330
SN - 0947-8396
VL - 130
JO - Applied Physics A: Materials Science and Processing
JF - Applied Physics A: Materials Science and Processing
IS - 8
M1 - 542
ER -