Electrochemical measurements for the corrosion inhibition of mild steel in 1 M hydrochloric acid by using an aromatic hydrazide derivative

P. Preethi Kumari; Prakash Shetty; Suma A. Rao

doi:10.1016/j.arabjc.2014.09.005

Electrochemical measurements for the corrosion inhibition of mild steel in 1 M hydrochloric acid by using an aromatic hydrazide derivative

P. Preethi Kumari, Prakash Shetty^*, Suma A. Rao

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

164 Citations (Scopus)

Abstract

The influence of an aromatic hydrazide derivative, 2-(3,4,5-trimethoxybenzylidene) hydrazinecarbothioamide (TMBHC) as corrosion inhibitor on mild steel in 1 M hydrochloric acid was studied by Tafel polarization and electrochemical impedance spectroscopy (EIS) technique. The results showed that the inhibition efficiency (% IE) of TMBHC increased with increasing inhibitor concentrations and also with increase in temperatures. TMBHC acted as a mixed type of inhibitor and its adsorption on mild steel surface was found to follow Langmuir's adsorption isotherm. The evaluation of thermodynamic and activation parameters indicated that the adsorption of TMBHC takes place through chemisorption. The formation of protective film was further confirmed by scanning electron microscopy (SEM).

Original language	English
Pages (from-to)	653-663
Number of pages	11
Journal	Arabian Journal of Chemistry
Volume	10
Issue number	5
DOIs	https://doi.org/10.1016/j.arabjc.2014.09.005
Publication status	Published - 01-07-2017

All Science Journal Classification (ASJC) codes

General Chemistry
General Chemical Engineering

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10.1016/j.arabjc.2014.09.005

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title = "Electrochemical measurements for the corrosion inhibition of mild steel in 1 M hydrochloric acid by using an aromatic hydrazide derivative",

abstract = "The influence of an aromatic hydrazide derivative, 2-(3,4,5-trimethoxybenzylidene) hydrazinecarbothioamide (TMBHC) as corrosion inhibitor on mild steel in 1 M hydrochloric acid was studied by Tafel polarization and electrochemical impedance spectroscopy (EIS) technique. The results showed that the inhibition efficiency (% IE) of TMBHC increased with increasing inhibitor concentrations and also with increase in temperatures. TMBHC acted as a mixed type of inhibitor and its adsorption on mild steel surface was found to follow Langmuir's adsorption isotherm. The evaluation of thermodynamic and activation parameters indicated that the adsorption of TMBHC takes place through chemisorption. The formation of protective film was further confirmed by scanning electron microscopy (SEM).",

author = "{Preethi Kumari}, P. and Prakash Shetty and Rao, {Suma A.}",

note = "Publisher Copyright: {\textcopyright} 2014 King Saud University",

year = "2017",

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doi = "10.1016/j.arabjc.2014.09.005",

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T1 - Electrochemical measurements for the corrosion inhibition of mild steel in 1 M hydrochloric acid by using an aromatic hydrazide derivative

AU - Preethi Kumari, P.

AU - Shetty, Prakash

AU - Rao, Suma A.

PY - 2017/7/1

Y1 - 2017/7/1

N2 - The influence of an aromatic hydrazide derivative, 2-(3,4,5-trimethoxybenzylidene) hydrazinecarbothioamide (TMBHC) as corrosion inhibitor on mild steel in 1 M hydrochloric acid was studied by Tafel polarization and electrochemical impedance spectroscopy (EIS) technique. The results showed that the inhibition efficiency (% IE) of TMBHC increased with increasing inhibitor concentrations and also with increase in temperatures. TMBHC acted as a mixed type of inhibitor and its adsorption on mild steel surface was found to follow Langmuir's adsorption isotherm. The evaluation of thermodynamic and activation parameters indicated that the adsorption of TMBHC takes place through chemisorption. The formation of protective film was further confirmed by scanning electron microscopy (SEM).

AB - The influence of an aromatic hydrazide derivative, 2-(3,4,5-trimethoxybenzylidene) hydrazinecarbothioamide (TMBHC) as corrosion inhibitor on mild steel in 1 M hydrochloric acid was studied by Tafel polarization and electrochemical impedance spectroscopy (EIS) technique. The results showed that the inhibition efficiency (% IE) of TMBHC increased with increasing inhibitor concentrations and also with increase in temperatures. TMBHC acted as a mixed type of inhibitor and its adsorption on mild steel surface was found to follow Langmuir's adsorption isotherm. The evaluation of thermodynamic and activation parameters indicated that the adsorption of TMBHC takes place through chemisorption. The formation of protective film was further confirmed by scanning electron microscopy (SEM).

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JF - Arabian Journal of Chemistry

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Electrochemical measurements for the corrosion inhibition of mild steel in 1 M hydrochloric acid by using an aromatic hydrazide derivative

Abstract

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