TY - JOUR
T1 - Embellishing 2-D MoS2Nanosheets on Lotus Thread Devices for Enhanced Hydrophobicity and Antimicrobial Activity
AU - Selvam, Govarthini Seerangan
AU - Dheivasigamani, Thangaraju
AU - Prabhu, Anusha
AU - Mani, Naresh Kumar
N1 - Funding Information:
D.T. sincerely thanks the Science and Engineering Research Board (ECR/2017/002974), Department of Science and Technology, Government of India, for the financial support. N.K.M. and A.P. acknowledge the financial support from Vision Group on Science and Technology, Government of Karnataka under SMYSR and RGS/F Scheme [Sanction Letter no.: KSTePS/VGST/SMYSR-2016-17/GRD-595/2017-18, KSTePS/VGSTRGS/F/GRD No.711/201711–18]. We extend our special thanks to the Department of Biotechnology, Manipal Institute of Technology.
Publisher Copyright:
© 2022 American Chemical Society. All rights reserved.
PY - 2022/7/19
Y1 - 2022/7/19
N2 - Herein, we report cellulose-based threads from Indian sacred Lotus (Nelumbo nucifera) of the Nymphaceae family embellished with MoS2nanosheets for its enhanced hydrophobic and antimicrobial properties. MoS2nanosheets synthesized by a coprecipitation method using sodium molybdate dihydrate (Na2MoO4·2H2O) and thioacetamide (CH3CSNH2) were used as a sourse for MoS2particle growth with cellulose threads extracted from lotus peduncles. The size, crystallinity, and morphology of pure and MoS2-coated fibers were studied using X-ray diffractometry (XRD) and scanning electron microscopy (SEM). the XRD pattern of pure lotus threads showed a semicrystalline nature, and the threads@MoS2composite showed more crystallinity than the pure threads. SEM depicts that pure lotus threads possess a smooth surface, and the MoS2nanosheets growth can be easily identified on the threads@MoS2. Further, the presence of MoS2nanosheets on threads was confirmed with EDX elemental analysis. Antimicrobial studies with Escherichia coli and Candida albicans reveal that threads@MoS2have better resistance than its counterpart, i.e., pure threads. MoS2sheets play a predominant role in restricting the wicking capability of the pure threads due to their enhanced hydrophobic property. The water absorbency assay denotes the absorption rate of threads@MoS2to 80%, and threads@MoS2shows no penetration for the observed 60 min, thus confirming its wicking restriction. The contact angle for threads@MoS2is 128°, indicating its improved hydrophobicity.
AB - Herein, we report cellulose-based threads from Indian sacred Lotus (Nelumbo nucifera) of the Nymphaceae family embellished with MoS2nanosheets for its enhanced hydrophobic and antimicrobial properties. MoS2nanosheets synthesized by a coprecipitation method using sodium molybdate dihydrate (Na2MoO4·2H2O) and thioacetamide (CH3CSNH2) were used as a sourse for MoS2particle growth with cellulose threads extracted from lotus peduncles. The size, crystallinity, and morphology of pure and MoS2-coated fibers were studied using X-ray diffractometry (XRD) and scanning electron microscopy (SEM). the XRD pattern of pure lotus threads showed a semicrystalline nature, and the threads@MoS2composite showed more crystallinity than the pure threads. SEM depicts that pure lotus threads possess a smooth surface, and the MoS2nanosheets growth can be easily identified on the threads@MoS2. Further, the presence of MoS2nanosheets on threads was confirmed with EDX elemental analysis. Antimicrobial studies with Escherichia coli and Candida albicans reveal that threads@MoS2have better resistance than its counterpart, i.e., pure threads. MoS2sheets play a predominant role in restricting the wicking capability of the pure threads due to their enhanced hydrophobic property. The water absorbency assay denotes the absorption rate of threads@MoS2to 80%, and threads@MoS2shows no penetration for the observed 60 min, thus confirming its wicking restriction. The contact angle for threads@MoS2is 128°, indicating its improved hydrophobicity.
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U2 - 10.1021/acsomega.2c02337
DO - 10.1021/acsomega.2c02337
M3 - Article
AN - SCOPUS:85135927698
SN - 2470-1343
VL - 7
SP - 24606
EP - 24613
JO - ACS Omega
JF - ACS Omega
IS - 28
ER -