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Free volume dependent fluorescence property of PMMA composite: Positron annihilation studies

  • V. Ravindrachary*
  • , S. D. Praveena
  • , R. F. Bhajantri
  • , Ismayil
  • , Vincent Crasta
  • *Corresponding author for this work

    Research output: Chapter in Book/Report/Conference proceedingConference contribution

    Abstract

    The free volume related fluorescence properties of chalcone chromophore [1-(4-methylphenyl)-3-(4-N, N, dimethylaminophenyl)-2-propen-1-one doped Poly(methyl methacrylate) have been studied using fluorescence spectroscopy and Positron Annihilation lifetime spectroscopy techniques. The fluorescence spectra show that the fluorescence behavior depends on the free volume dependent polymer microstructure and varies with dopant concentration with in the composite. The origin and variation of fluorescence is understood by twisted internal charge transfer state as well as free volume. The Positron annihilation study shows that the free volume related microstructure of the composite is vary with doping level.

    Original languageEnglish
    Title of host publicationSolid State Physics - Proceedings of the 57th DAE Solid State Physics Symposium 2012
    Pages126-127
    Number of pages2
    Volume1512
    DOIs
    Publication statusPublished - 15-03-2013
    Event57th DAE Solid State Physics Symposium 2012 - Bombay, Mumbai, India
    Duration: 03-12-201207-12-2012

    Publication series

    NameAIP Conference Proceedings
    Volume1512
    ISSN (Print)0094-243X
    ISSN (Electronic)1551-7616

    Conference

    Conference57th DAE Solid State Physics Symposium 2012
    Country/TerritoryIndia
    CityBombay, Mumbai
    Period03-12-1207-12-12

    All Science Journal Classification (ASJC) codes

    • General Physics and Astronomy

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