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Free volume related electrical properties of sodium alginate/LiClO 4 solid polyectrolyte

  • S. D. Praveena
  • , V. Ravindrachary*
  • , R. F. Bhajantri
  • , Ismayil
  • *Corresponding author for this work

    Research output: Chapter in Book/Report/Conference proceedingConference contribution

    Abstract

    The free volume related microstructural properties of sodium alginate/lithium perchlorate solid polyelectrolyte have been studied using Positron Annihilation spectroscopy (PALS), conductivity techniques. PALS studies reveal that the o-free volume size and its number density vary with LiClO 4 doping level. This study indicates that the doping modified the free volume related microstructure and enhances the amorphous nature of the film due to the complete dissolution of LiClO4 in NaAlg. From the conductivity studies it is clear that the ionic conductivity increases with doping level and its variation is understood based on ionic mobility due to segmental as well as Cohen-Turnbull model of the free volume dependent ionic transport.

    Original languageEnglish
    Title of host publicationSolid State Physics - Proceedings of the 57th DAE Solid State Physics Symposium 2012
    Pages128-129
    Number of pages2
    Volume1512
    DOIs
    Publication statusPublished - 15-03-2013
    Event57th DAE Solid State Physics Symposium 2012 - Bombay, Mumbai, India
    Duration: 03-12-201207-12-2012

    Publication series

    NameAIP Conference Proceedings
    Volume1512
    ISSN (Print)0094-243X
    ISSN (Electronic)1551-7616

    Conference

    Conference57th DAE Solid State Physics Symposium 2012
    Country/TerritoryIndia
    CityBombay, Mumbai
    Period03-12-1207-12-12

    All Science Journal Classification (ASJC) codes

    • General Physics and Astronomy

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