Methyl 2,6-bis-[(5-bromo-4,6-dimethoxypyrimidin-2-yl)oxy]benzoate

Hoong Kun Fun; Jia Hao Goh; Sankappa Rai; Arun M. Isloor; Prakash Shetty

doi:10.1107/S1600536810024724

Methyl 2,6-bis-[(5-bromo-4,6-dimethoxypyrimidin-2-yl)oxy]benzoate

Hoong Kun Fun^*
, Jia Hao Goh
, Sankappa Rai
, Arun M. Isloor
, Prakash Shetty

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

In the title compound, C₂₀H₁₈Br₂N ₄O₈, the inter-planar angle of the pyrimidine rings is 75.1 (2)°. The central benzene ring is inclined at inter-planar angles of 66.5 (2) and 71.9 (2)° with respect to the two pyrimidine rings. In the crystal structure, adjacent molecules are connected into two-molecule-thick arrays parallel to the bc plane via short Br⋯Br [3.5328 (12) Å] and Br⋯O [3.206 (3) and 3.301 (4) Å] inter-actions. A weak inter-molecular π-π aromatic stacking inter-action [centroid-centroid distance = 3.526 (3) Å] is also observed.

Original language	English
Pages (from-to)	o1871
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	66
Issue number	7
DOIs	https://doi.org/10.1107/S1600536810024724
Publication status	Published - 14-07-2010

All Science Journal Classification (ASJC) codes

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1107/S1600536810024724

Cite this

@article{b343f4619a944a068861a408dfcee9b9,

title = "Methyl 2,6-bis-[(5-bromo-4,6-dimethoxypyrimidin-2-yl)oxy]benzoate",

abstract = "In the title compound, C20H18Br2N 4O8, the inter-planar angle of the pyrimidine rings is 75.1 (2)°. The central benzene ring is inclined at inter-planar angles of 66.5 (2) and 71.9 (2)° with respect to the two pyrimidine rings. In the crystal structure, adjacent molecules are connected into two-molecule-thick arrays parallel to the bc plane via short Br⋯Br [3.5328 (12) {\AA}] and Br⋯O [3.206 (3) and 3.301 (4) {\AA}] inter-actions. A weak inter-molecular π-π aromatic stacking inter-action [centroid-centroid distance = 3.526 (3) {\AA}] is also observed.",

author = "Fun, \{Hoong Kun\} and Goh, \{Jia Hao\} and Sankappa Rai and Isloor, \{Arun M.\} and Prakash Shetty",

year = "2010",

month = jul,

day = "14",

doi = "10.1107/S1600536810024724",

language = "English",

volume = "66",

pages = "o1871",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "7",

}

TY - JOUR

T1 - Methyl 2,6-bis-[(5-bromo-4,6-dimethoxypyrimidin-2-yl)oxy]benzoate

AU - Fun, Hoong Kun

AU - Goh, Jia Hao

AU - Rai, Sankappa

AU - Isloor, Arun M.

AU - Shetty, Prakash

PY - 2010/7/14

Y1 - 2010/7/14

N2 - In the title compound, C20H18Br2N 4O8, the inter-planar angle of the pyrimidine rings is 75.1 (2)°. The central benzene ring is inclined at inter-planar angles of 66.5 (2) and 71.9 (2)° with respect to the two pyrimidine rings. In the crystal structure, adjacent molecules are connected into two-molecule-thick arrays parallel to the bc plane via short Br⋯Br [3.5328 (12) Å] and Br⋯O [3.206 (3) and 3.301 (4) Å] inter-actions. A weak inter-molecular π-π aromatic stacking inter-action [centroid-centroid distance = 3.526 (3) Å] is also observed.

AB - In the title compound, C20H18Br2N 4O8, the inter-planar angle of the pyrimidine rings is 75.1 (2)°. The central benzene ring is inclined at inter-planar angles of 66.5 (2) and 71.9 (2)° with respect to the two pyrimidine rings. In the crystal structure, adjacent molecules are connected into two-molecule-thick arrays parallel to the bc plane via short Br⋯Br [3.5328 (12) Å] and Br⋯O [3.206 (3) and 3.301 (4) Å] inter-actions. A weak inter-molecular π-π aromatic stacking inter-action [centroid-centroid distance = 3.526 (3) Å] is also observed.

UR - https://www.scopus.com/pages/publications/77954415306

UR - https://www.scopus.com/pages/publications/77954415306#tab=citedBy

U2 - 10.1107/S1600536810024724

DO - 10.1107/S1600536810024724

M3 - Article

AN - SCOPUS:77954415306

SN - 1600-5368

VL - 66

SP - o1871

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 7

ER -

Methyl 2,6-bis-[(5-bromo-4,6-dimethoxypyrimidin-2-yl)oxy]benzoate

Abstract

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