TY - JOUR
T1 - Methyl 2,6-bis-[(5-chloro-4,6-dimethoxypyrimidin-2-yl)oxy]benzoate
AU - Fun, Hoong Kun
AU - Goh, Jia Hao
AU - Rai, Sankappa
AU - Isloor, Arun M.
AU - Shetty, Prakash
PY - 2010/7/14
Y1 - 2010/7/14
N2 - In the title compound, C20H18Cl2N 4O8, the two pyrimidine rings are inclined at dihedral angles of 66.68 (5) and 71.91 (6)° with respect to the central benzene ring. In the crystal structure, inter-molecular C-H⋯N hydrogen bonds link neighbouring molecules into a ribbon-like structure along the b axis. The ribbons are inter-connected into a two-dimensional network parallel to the bc plane by short inter-molecular Cl⋯Cl [3.4427 (6) Å] and Cl⋯O [3.1420 (9) and 3.1750 (11) Å] inter-actions. The crystal structure is further stabilized by inter-molecular π-π inter-actions [centroid-centroid distance 3.4552 (8) Å] involving the pyrimidine rings.
AB - In the title compound, C20H18Cl2N 4O8, the two pyrimidine rings are inclined at dihedral angles of 66.68 (5) and 71.91 (6)° with respect to the central benzene ring. In the crystal structure, inter-molecular C-H⋯N hydrogen bonds link neighbouring molecules into a ribbon-like structure along the b axis. The ribbons are inter-connected into a two-dimensional network parallel to the bc plane by short inter-molecular Cl⋯Cl [3.4427 (6) Å] and Cl⋯O [3.1420 (9) and 3.1750 (11) Å] inter-actions. The crystal structure is further stabilized by inter-molecular π-π inter-actions [centroid-centroid distance 3.4552 (8) Å] involving the pyrimidine rings.
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U2 - 10.1107/S1600536810024785
DO - 10.1107/S1600536810024785
M3 - Article
AN - SCOPUS:77954415117
SN - 1600-5368
VL - 66
SP - o1869-o1870
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 7
ER -