TY - JOUR
T1 - One-step bacterial assisted synthesis of CdS/rGO nanocomposite as Hydrogen production catalyst
AU - Hareesh, K.
AU - Dhole, Sanjay D.
AU - Phase, Deodatta M.
AU - Williams, Jim F.
N1 - Funding Information:
Authors thank Mrs. Anuradha and Mrs. Jyotsana Dixit for their help in preparing bacterial bio-mass. KH acknowledge DST-SERB (No. ECR/2017/002788), Government of India, for financial assistance.
Funding Information:
Authors thank Mrs. Anuradha and Mrs. Jyotsana Dixit for their help in preparing bacterial bio-mass. KH acknowledge DST-SERB (No. ECR/2017/002788 ), Government of India, for financial assistance.
Publisher Copyright:
© 2018 Elsevier Ltd
PY - 2019/2
Y1 - 2019/2
N2 - One-step E-Coli bacterial assisted method was employed to synthesize Cadmium Sulfide/reduced graphene oxide (CdS/rGO) nanocomposite and its photocatalytic Hydrogen production activity was studied under visible light irradiation. The loading of rGO in nanocomposite was varied to study its effect on photocatalytic Hydrogen production. Among all, CdS/rGO (2 wt%) showed highest photocatalytic activity i.e. it produced 500 μmolg−1 h-1 of Hydrogen. The enhanced photocatalytic activity of CdS/rGO (2 wt%) was due to decrease in its work function to 3.98 eV and good efficiency in the separation of photogenerated charge carriers, which in turn indicate the increased lifetime of charge carriers. Furthermore, the CdS/rGO (2 wt%) nanocomposite showed excellent photocatalytic stability for Hydrogen production due to the presence of rGO, which protects the CdS nanoparticles from photo-corrosion. It is anticipated that this work could enhance the information on photocatalytic mechanism of CdS/rGO nanocomposite towards Hydrogen production under visible light irradiation.
AB - One-step E-Coli bacterial assisted method was employed to synthesize Cadmium Sulfide/reduced graphene oxide (CdS/rGO) nanocomposite and its photocatalytic Hydrogen production activity was studied under visible light irradiation. The loading of rGO in nanocomposite was varied to study its effect on photocatalytic Hydrogen production. Among all, CdS/rGO (2 wt%) showed highest photocatalytic activity i.e. it produced 500 μmolg−1 h-1 of Hydrogen. The enhanced photocatalytic activity of CdS/rGO (2 wt%) was due to decrease in its work function to 3.98 eV and good efficiency in the separation of photogenerated charge carriers, which in turn indicate the increased lifetime of charge carriers. Furthermore, the CdS/rGO (2 wt%) nanocomposite showed excellent photocatalytic stability for Hydrogen production due to the presence of rGO, which protects the CdS nanoparticles from photo-corrosion. It is anticipated that this work could enhance the information on photocatalytic mechanism of CdS/rGO nanocomposite towards Hydrogen production under visible light irradiation.
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U2 - 10.1016/j.materresbull.2018.10.012
DO - 10.1016/j.materresbull.2018.10.012
M3 - Article
AN - SCOPUS:85055041833
SN - 0025-5408
VL - 110
SP - 82
EP - 89
JO - Materials Research Bulletin
JF - Materials Research Bulletin
ER -