Oxomolybdenum(V) complexes of 2-benzothiazolyl hydrazones

Sharada R. Girish; Vidyanand K. Revankar; Vinayak B. Mahale

Oxomolybdenum(V) complexes of 2-benzothiazolyl hydrazones

Sharada R. Girish, Vidyanand K. Revankar, Vinayak B. Mahale

International Centre for Applied Sciences, Manipal

Research output: Contribution to journal › Article › peer-review

12 Citations (SciVal)

Abstract

Oxomolybdenum(V) complexes of general formulae [Mo₂O₃L₂Cl₂]H₂O and [Mo₂O₃L₂(OH)₂(H₂O) ₂] (LH = hydrazones derived from 2-hydrazinobenzothiazole with salicyladehyde, 5-methyl-, 5-chloro-, 5-bromo-, 3-methoxysalicyldehyde and 2-hydroxy-1-naphthaldehyde) have been prepared and characterized by elemental analysis, conductivities, magnetic moments, thermal studies, and i.r., u.v.-vis. and e.p.r. spectra. The data suggest that the complexes are non-electrolytes, paramagnetic and have distorted octahedral structures with possible metal-metal interactions via oxo bridging.

Original language	English
Pages (from-to)	401-405
Number of pages	5
Journal	Transition Metal Chemistry
Volume	21
Issue number	5
Publication status	Published - 10-1996

All Science Journal Classification (ASJC) codes

Inorganic Chemistry
Metals and Alloys
Materials Chemistry

Cite this

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title = "Oxomolybdenum(V) complexes of 2-benzothiazolyl hydrazones",

abstract = "Oxomolybdenum(V) complexes of general formulae [Mo2O3L2Cl2]H2O and [Mo2O3L2(OH)2(H2O) 2] (LH = hydrazones derived from 2-hydrazinobenzothiazole with salicyladehyde, 5-methyl-, 5-chloro-, 5-bromo-, 3-methoxysalicyldehyde and 2-hydroxy-1-naphthaldehyde) have been prepared and characterized by elemental analysis, conductivities, magnetic moments, thermal studies, and i.r., u.v.-vis. and e.p.r. spectra. The data suggest that the complexes are non-electrolytes, paramagnetic and have distorted octahedral structures with possible metal-metal interactions via oxo bridging.",

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year = "1996",

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journal = "Transition Metal Chemistry",

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T1 - Oxomolybdenum(V) complexes of 2-benzothiazolyl hydrazones

AU - Girish, Sharada R.

AU - Revankar, Vidyanand K.

AU - Mahale, Vinayak B.

PY - 1996/10

Y1 - 1996/10

N2 - Oxomolybdenum(V) complexes of general formulae [Mo2O3L2Cl2]H2O and [Mo2O3L2(OH)2(H2O) 2] (LH = hydrazones derived from 2-hydrazinobenzothiazole with salicyladehyde, 5-methyl-, 5-chloro-, 5-bromo-, 3-methoxysalicyldehyde and 2-hydroxy-1-naphthaldehyde) have been prepared and characterized by elemental analysis, conductivities, magnetic moments, thermal studies, and i.r., u.v.-vis. and e.p.r. spectra. The data suggest that the complexes are non-electrolytes, paramagnetic and have distorted octahedral structures with possible metal-metal interactions via oxo bridging.

AB - Oxomolybdenum(V) complexes of general formulae [Mo2O3L2Cl2]H2O and [Mo2O3L2(OH)2(H2O) 2] (LH = hydrazones derived from 2-hydrazinobenzothiazole with salicyladehyde, 5-methyl-, 5-chloro-, 5-bromo-, 3-methoxysalicyldehyde and 2-hydroxy-1-naphthaldehyde) have been prepared and characterized by elemental analysis, conductivities, magnetic moments, thermal studies, and i.r., u.v.-vis. and e.p.r. spectra. The data suggest that the complexes are non-electrolytes, paramagnetic and have distorted octahedral structures with possible metal-metal interactions via oxo bridging.

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Oxomolybdenum(V) complexes of 2-benzothiazolyl hydrazones

Abstract

All Science Journal Classification (ASJC) codes

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