Oxomolybdenum(V) complexes of 2-benzothiazolyl hydrazones

Sharada R. Girish; Vidyanand K. Revankar; Vinayak B. Mahale

doi:10.1007/BF00140779

Oxomolybdenum(V) complexes of 2-benzothiazolyl hydrazones

Sharada R. Girish
, Vidyanand K. Revankar
, Vinayak B. Mahale^*

^*Corresponding author for this work

International Centre for Applied Sciences, Manipal

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

Oxomolybdenum(V) complexes of general formulae [Mo₂O₃L₂Cl₂]H₂O and [Mo₂O₃L₂(OH)₂(H₂O) ₂] (LH = hydrazones derived from 2-hydrazinobenzothiazole with salicyladehyde, 5-methyl-, 5-chloro-, 5-bromo-, 3-methoxysalicyldehyde and 2-hydroxy-1-naphthaldehyde) have been prepared and characterized by elemental analysis, conductivities, magnetic moments, thermal studies, and i.r., u.v.-vis. and e.p.r. spectra. The data suggest that the complexes are non-electrolytes, paramagnetic and have distorted octahedral structures with possible metal-metal interactions via oxo bridging.

Original language	English
Pages (from-to)	401-405
Number of pages	5
Journal	Transition Metal Chemistry
Volume	21
Issue number	5
DOIs	https://doi.org/10.1007/BF00140779
Publication status	Published - 10-1996

All Science Journal Classification (ASJC) codes

Inorganic Chemistry
Metals and Alloys
Materials Chemistry

Access to Document

10.1007/BF00140779

Cite this

@article{e0d4a188dcac47b6a8d368074aa75191,

title = "Oxomolybdenum(V) complexes of 2-benzothiazolyl hydrazones",

abstract = "Oxomolybdenum(V) complexes of general formulae [Mo2O3L2Cl2]H2O and [Mo2O3L2(OH)2(H2O) 2] (LH = hydrazones derived from 2-hydrazinobenzothiazole with salicyladehyde, 5-methyl-, 5-chloro-, 5-bromo-, 3-methoxysalicyldehyde and 2-hydroxy-1-naphthaldehyde) have been prepared and characterized by elemental analysis, conductivities, magnetic moments, thermal studies, and i.r., u.v.-vis. and e.p.r. spectra. The data suggest that the complexes are non-electrolytes, paramagnetic and have distorted octahedral structures with possible metal-metal interactions via oxo bridging.",

author = "Girish, \{Sharada R.\} and Revankar, \{Vidyanand K.\} and Mahale, \{Vinayak B.\}",

year = "1996",

month = oct,

doi = "10.1007/BF00140779",

language = "English",

volume = "21",

pages = "401--405",

journal = "Transition Metal Chemistry",

issn = "0340-4285",

publisher = "Springer Netherlands",

number = "5",

}

TY - JOUR

T1 - Oxomolybdenum(V) complexes of 2-benzothiazolyl hydrazones

AU - Girish, Sharada R.

AU - Revankar, Vidyanand K.

AU - Mahale, Vinayak B.

PY - 1996/10

Y1 - 1996/10

N2 - Oxomolybdenum(V) complexes of general formulae [Mo2O3L2Cl2]H2O and [Mo2O3L2(OH)2(H2O) 2] (LH = hydrazones derived from 2-hydrazinobenzothiazole with salicyladehyde, 5-methyl-, 5-chloro-, 5-bromo-, 3-methoxysalicyldehyde and 2-hydroxy-1-naphthaldehyde) have been prepared and characterized by elemental analysis, conductivities, magnetic moments, thermal studies, and i.r., u.v.-vis. and e.p.r. spectra. The data suggest that the complexes are non-electrolytes, paramagnetic and have distorted octahedral structures with possible metal-metal interactions via oxo bridging.

AB - Oxomolybdenum(V) complexes of general formulae [Mo2O3L2Cl2]H2O and [Mo2O3L2(OH)2(H2O) 2] (LH = hydrazones derived from 2-hydrazinobenzothiazole with salicyladehyde, 5-methyl-, 5-chloro-, 5-bromo-, 3-methoxysalicyldehyde and 2-hydroxy-1-naphthaldehyde) have been prepared and characterized by elemental analysis, conductivities, magnetic moments, thermal studies, and i.r., u.v.-vis. and e.p.r. spectra. The data suggest that the complexes are non-electrolytes, paramagnetic and have distorted octahedral structures with possible metal-metal interactions via oxo bridging.

UR - https://www.scopus.com/pages/publications/0346886280

UR - https://www.scopus.com/pages/publications/0346886280#tab=citedBy

U2 - 10.1007/BF00140779

DO - 10.1007/BF00140779

M3 - Article

AN - SCOPUS:0346886280

SN - 0340-4285

VL - 21

SP - 401

EP - 405

JO - Transition Metal Chemistry

JF - Transition Metal Chemistry

IS - 5

ER -

Oxomolybdenum(V) complexes of 2-benzothiazolyl hydrazones

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this