TY - JOUR
T1 - Physical, optical, thermoanalytical, and radiation response study of Eu2O3-doped zinc fluoro-telluroborate glasses
AU - Wagh, A.
AU - D’Souza, A. N.
AU - Karunakara, N.
AU - Shailaja, H.
AU - Raviprakash, Y.
AU - Kamath, S. D.
N1 - Publisher Copyright:
© 2023, The Author(s).
PY - 2023
Y1 - 2023
N2 - In the present study, Eu3+-doped zinc fluoro-telluroborate transparent glasses were prepared by the conventional melt−quench technique. Their density and refractive index values were measured, and using these values, different physical parameters (number density, oxygen packing density, no. of bonds/vol, etc.) were calculated and analysed. The XRD pattern displayed a disordered atomic arrangement in the glass network. The EDS spectra proved the purity of the samples exhibiting only those elements used during the synthesis. The good solubility of Eu3+ ions in zinc fluoro-telluroborate glasses was analysed through fine absorption peaks in the UV−Vis−NIR range. The absorption intensities increased in all samples up to 3.0 mol% of Eu3+-doping concentration. The stabilities of the samples, such as ∆T ~ (144–156) °C and Hr ~ 2.33–4.00, calculated using characteristic temperatures (Tg, Tx, Tc, Tm) from DSC studies exhibited their promising candidature in a high-temperature environment. The Eu7 (Eu3+ with 3.0 mol%) glass confirmed better attenuation properties (LAC, Zeff, HVL, MFP) compared to other composition (0–2.5 mol%) glasses.
AB - In the present study, Eu3+-doped zinc fluoro-telluroborate transparent glasses were prepared by the conventional melt−quench technique. Their density and refractive index values were measured, and using these values, different physical parameters (number density, oxygen packing density, no. of bonds/vol, etc.) were calculated and analysed. The XRD pattern displayed a disordered atomic arrangement in the glass network. The EDS spectra proved the purity of the samples exhibiting only those elements used during the synthesis. The good solubility of Eu3+ ions in zinc fluoro-telluroborate glasses was analysed through fine absorption peaks in the UV−Vis−NIR range. The absorption intensities increased in all samples up to 3.0 mol% of Eu3+-doping concentration. The stabilities of the samples, such as ∆T ~ (144–156) °C and Hr ~ 2.33–4.00, calculated using characteristic temperatures (Tg, Tx, Tc, Tm) from DSC studies exhibited their promising candidature in a high-temperature environment. The Eu7 (Eu3+ with 3.0 mol%) glass confirmed better attenuation properties (LAC, Zeff, HVL, MFP) compared to other composition (0–2.5 mol%) glasses.
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U2 - 10.1007/s12648-022-02540-8
DO - 10.1007/s12648-022-02540-8
M3 - Article
AN - SCOPUS:85145577482
SN - 0252-9262
JO - Indian Journal of Physics
JF - Indian Journal of Physics
ER -