Reactivity of tricarbonyl(η5-cyclopentadienyl)(dimethyldithiocarbamato)tungsten towards coordinatively unsaturated species

Pradeep Mathur; B. H.S. Thimmappa

doi:10.1016/S0020-1693(00)86021-1

Reactivity of tricarbonyl(η⁵-cyclopentadienyl)(dimethyldithiocarbamato)tungsten towards coordinatively unsaturated species

Pradeep Mathur, B. H.S. Thimmappa

Department of Chemistry, Manipal Institute of Technology, Manipal

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Visible light irradiation of solutions containing [(η⁵-C₅H₅)(CO)₃ WSC(S)NMe₂] (1) and Fe₂(CO)₉ or Mn₂(CO)₁₀ leads to a transmetallation type of reaction and formation of Fe(S₂CNMe₂)₂ and Mn(CO)₄(S₂CNMe₂) respectively. However, the reaction or 1 with M(PPh₃)₄, M = Pt, or Pd, leads to conversion to the dicarbonyl chelate complex [(η⁵C₂H₅(CO)₂ W(S₂CNMe₂)].

Original language	English
Pages (from-to)	119-122
Number of pages	4
Journal	Inorganica Chimica Acta
Volume	148
Issue number	1
DOIs	https://doi.org/10.1016/S0020-1693(00)86021-1
Publication status	Published - 01-08-1988

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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title = "Reactivity of tricarbonyl(η5-cyclopentadienyl)(dimethyldithiocarbamato)tungsten towards coordinatively unsaturated species",

abstract = "Visible light irradiation of solutions containing [(η5-C5H5)(CO)3 WSC(S)NMe2] (1) and Fe2(CO)9 or Mn2(CO)10 leads to a transmetallation type of reaction and formation of Fe(S2CNMe2)2 and Mn(CO)4(S2CNMe2) respectively. However, the reaction or 1 with M(PPh3)4, M = Pt, or Pd, leads to conversion to the dicarbonyl chelate complex [(η5C2H5(CO)2 W(S2CNMe2)].",

author = "Pradeep Mathur and Thimmappa, {B. H.S.}",

year = "1988",

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doi = "10.1016/S0020-1693(00)86021-1",

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T1 - Reactivity of tricarbonyl(η5-cyclopentadienyl)(dimethyldithiocarbamato)tungsten towards coordinatively unsaturated species

AU - Mathur, Pradeep

AU - Thimmappa, B. H.S.

PY - 1988/8/1

Y1 - 1988/8/1

N2 - Visible light irradiation of solutions containing [(η5-C5H5)(CO)3 WSC(S)NMe2] (1) and Fe2(CO)9 or Mn2(CO)10 leads to a transmetallation type of reaction and formation of Fe(S2CNMe2)2 and Mn(CO)4(S2CNMe2) respectively. However, the reaction or 1 with M(PPh3)4, M = Pt, or Pd, leads to conversion to the dicarbonyl chelate complex [(η5C2H5(CO)2 W(S2CNMe2)].

AB - Visible light irradiation of solutions containing [(η5-C5H5)(CO)3 WSC(S)NMe2] (1) and Fe2(CO)9 or Mn2(CO)10 leads to a transmetallation type of reaction and formation of Fe(S2CNMe2)2 and Mn(CO)4(S2CNMe2) respectively. However, the reaction or 1 with M(PPh3)4, M = Pt, or Pd, leads to conversion to the dicarbonyl chelate complex [(η5C2H5(CO)2 W(S2CNMe2)].

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ER -

Reactivity of tricarbonyl(η⁵-cyclopentadienyl)(dimethyldithiocarbamato)tungsten towards coordinatively unsaturated species

Abstract

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