Spectrophotometric determination of palladium(II) using piperonal thiosemicarbazone

Prakash Shetty; A. Nityananda Shetty; R. V. Gadag

Spectrophotometric determination of palladium(II) using piperonal thiosemicarbazone

Prakash Shetty, A. Nityananda Shetty^*, R. V. Gadag

^*Corresponding author for this work

Department of Chemistry, Manipal Institute of Technology, Manipal

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

A simple, rapid, selective and sensitive spectrophotometric method for the determination of palladium is proposed using piperonal thiosemicarbazone (PATS) as a reagent. The reagent forms a 1:2 complex (Pd:Reagent) with palladium. The yellow complex is soluble in 32-40% ethanol and has an absorption maximum at 363 nm. Beer's law is obeyed upto 3.85 ppm of palladium and the optimum concentration range is 0.5-2.45 ppm of Pd. The molar absorptivity and Sandell's sensitivity are 3. 80 x 10⁴ dm³ mol^-1 cm ^-1 and 2.8 x 10^-3 μg cm^-2, respectively. The experimental conditions for complete colour development and the interference from various ions are investigated. The method is used for the determination of palladium in its complexes and synthetic mixtures.

Original language	English
Pages (from-to)	287-290
Number of pages	4
Journal	Indian Journal of Chemical Technology
Volume	10
Issue number	3
Publication status	Published - 01-05-2003

All Science Journal Classification (ASJC) codes

General Chemistry
General Chemical Engineering

Cite this

@article{51945655d2024fb3bfd80210dbdaef19,

title = "Spectrophotometric determination of palladium(II) using piperonal thiosemicarbazone",

abstract = "A simple, rapid, selective and sensitive spectrophotometric method for the determination of palladium is proposed using piperonal thiosemicarbazone (PATS) as a reagent. The reagent forms a 1:2 complex (Pd:Reagent) with palladium. The yellow complex is soluble in 32-40\% ethanol and has an absorption maximum at 363 nm. Beer's law is obeyed upto 3.85 ppm of palladium and the optimum concentration range is 0.5-2.45 ppm of Pd. The molar absorptivity and Sandell's sensitivity are 3. 80 x 104 dm3 mol-1 cm -1 and 2.8 x 10-3 μg cm-2, respectively. The experimental conditions for complete colour development and the interference from various ions are investigated. The method is used for the determination of palladium in its complexes and synthetic mixtures.",

author = "Prakash Shetty and \{Nityananda Shetty\}, A. and Gadag, \{R. V.\}",

year = "2003",

month = may,

day = "1",

language = "English",

volume = "10",

pages = "287--290",

journal = "Indian Journal of Chemical Technology",

issn = "0971-457X",

publisher = "National Institute of Science Communication and Information Resources (NISCAIR)",

number = "3",

}

TY - JOUR

T1 - Spectrophotometric determination of palladium(II) using piperonal thiosemicarbazone

AU - Shetty, Prakash

AU - Nityananda Shetty, A.

AU - Gadag, R. V.

PY - 2003/5/1

Y1 - 2003/5/1

N2 - A simple, rapid, selective and sensitive spectrophotometric method for the determination of palladium is proposed using piperonal thiosemicarbazone (PATS) as a reagent. The reagent forms a 1:2 complex (Pd:Reagent) with palladium. The yellow complex is soluble in 32-40% ethanol and has an absorption maximum at 363 nm. Beer's law is obeyed upto 3.85 ppm of palladium and the optimum concentration range is 0.5-2.45 ppm of Pd. The molar absorptivity and Sandell's sensitivity are 3. 80 x 104 dm3 mol-1 cm -1 and 2.8 x 10-3 μg cm-2, respectively. The experimental conditions for complete colour development and the interference from various ions are investigated. The method is used for the determination of palladium in its complexes and synthetic mixtures.

AB - A simple, rapid, selective and sensitive spectrophotometric method for the determination of palladium is proposed using piperonal thiosemicarbazone (PATS) as a reagent. The reagent forms a 1:2 complex (Pd:Reagent) with palladium. The yellow complex is soluble in 32-40% ethanol and has an absorption maximum at 363 nm. Beer's law is obeyed upto 3.85 ppm of palladium and the optimum concentration range is 0.5-2.45 ppm of Pd. The molar absorptivity and Sandell's sensitivity are 3. 80 x 104 dm3 mol-1 cm -1 and 2.8 x 10-3 μg cm-2, respectively. The experimental conditions for complete colour development and the interference from various ions are investigated. The method is used for the determination of palladium in its complexes and synthetic mixtures.

UR - https://www.scopus.com/pages/publications/0141628539

UR - https://www.scopus.com/inward/citedby.url?scp=0141628539&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0141628539

SN - 0971-457X

VL - 10

SP - 287

EP - 290

JO - Indian Journal of Chemical Technology

JF - Indian Journal of Chemical Technology

IS - 3

ER -

Spectrophotometric determination of palladium(II) using piperonal thiosemicarbazone

Abstract

All Science Journal Classification (ASJC) codes

Other files and links

Fingerprint

Cite this