Studies of physicochemical characterization and pyrolysis behavior of low-value waste biomass using Thermogravimetric analyzer: evaluation of kinetic and thermodynamic parameters

Ahmad Nawaz; Ranjeet Kumar Mishra; Shivesh Sabbarwal; Pradeep Kumar

doi:10.1016/j.biteb.2021.100858

Studies of physicochemical characterization and pyrolysis behavior of low-value waste biomass using Thermogravimetric analyzer: evaluation of kinetic and thermodynamic parameters

Ahmad Nawaz
, Ranjeet Kumar Mishra
, Shivesh Sabbarwal
, Pradeep Kumar^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

65 Citations (Scopus)

Abstract

The current investigation demonstrated the physicochemical study, pyrolysis performance, and kinetic study of Lagerstroemia speciosa seed hull (LSH) biomass in a thermogravimetric analyzer under an inert ambiance. LSH sample was characterized by proximate study, elemental study, calorific value, biochemical analysis, and thermal stability study, whereas; isoconversional models such as Ozawa-Flynn-Wall (OFW), Kissinger-Akahira-Sunose (KAS), Vyazovkin (VZM), Tang method (TM), and Starink method (STM) were used for performing the kinetic study. The physicochemical study of LSH revealed its bioenergy capability to create renewable fuel and valued compounds. Further, isoconversional models such as OFW, KAS, TM, STM, and VZM yielded average activation energy of 164, 154.35, 154.63, 154.61, and 141.93 kJ/mol. The master plot and thermodynamic study of LSH confirmed that the pyrolysis process passed through multifaceted reaction mechanisms.

Original language	English
Article number	100858
Journal	Bioresource Technology Reports
Volume	16
DOIs	https://doi.org/10.1016/j.biteb.2021.100858
Publication status	Published - 12-2021

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

All Science Journal Classification (ASJC) codes

Bioengineering
Environmental Engineering
Renewable Energy, Sustainability and the Environment
Waste Management and Disposal

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10.1016/j.biteb.2021.100858

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@article{b164388848e448eab0055c73efc5b496,

title = "Studies of physicochemical characterization and pyrolysis behavior of low-value waste biomass using Thermogravimetric analyzer: evaluation of kinetic and thermodynamic parameters",

abstract = "The current investigation demonstrated the physicochemical study, pyrolysis performance, and kinetic study of Lagerstroemia speciosa seed hull (LSH) biomass in a thermogravimetric analyzer under an inert ambiance. LSH sample was characterized by proximate study, elemental study, calorific value, biochemical analysis, and thermal stability study, whereas; isoconversional models such as Ozawa-Flynn-Wall (OFW), Kissinger-Akahira-Sunose (KAS), Vyazovkin (VZM), Tang method (TM), and Starink method (STM) were used for performing the kinetic study. The physicochemical study of LSH revealed its bioenergy capability to create renewable fuel and valued compounds. Further, isoconversional models such as OFW, KAS, TM, STM, and VZM yielded average activation energy of 164, 154.35, 154.63, 154.61, and 141.93 kJ/mol. The master plot and thermodynamic study of LSH confirmed that the pyrolysis process passed through multifaceted reaction mechanisms.",

author = "Ahmad Nawaz and Mishra, \{Ranjeet Kumar\} and Shivesh Sabbarwal and Pradeep Kumar",

note = "Publisher Copyright: {\textcopyright} 2021 Elsevier Ltd",

year = "2021",

month = dec,

doi = "10.1016/j.biteb.2021.100858",

language = "English",

volume = "16",

journal = "Bioresource Technology Reports",

issn = "2589-014X",

publisher = "Elsevier Ltd",

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Studies of physicochemical characterization and pyrolysis behavior of low-value waste biomass using Thermogravimetric analyzer: evaluation of kinetic and thermodynamic parameters. / Nawaz, Ahmad; Mishra, Ranjeet Kumar; Sabbarwal, Shivesh et al.
In: Bioresource Technology Reports, Vol. 16, 100858, 12.2021.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Studies of physicochemical characterization and pyrolysis behavior of low-value waste biomass using Thermogravimetric analyzer

T2 - evaluation of kinetic and thermodynamic parameters

AU - Nawaz, Ahmad

AU - Mishra, Ranjeet Kumar

AU - Sabbarwal, Shivesh

AU - Kumar, Pradeep

PY - 2021/12

Y1 - 2021/12

N2 - The current investigation demonstrated the physicochemical study, pyrolysis performance, and kinetic study of Lagerstroemia speciosa seed hull (LSH) biomass in a thermogravimetric analyzer under an inert ambiance. LSH sample was characterized by proximate study, elemental study, calorific value, biochemical analysis, and thermal stability study, whereas; isoconversional models such as Ozawa-Flynn-Wall (OFW), Kissinger-Akahira-Sunose (KAS), Vyazovkin (VZM), Tang method (TM), and Starink method (STM) were used for performing the kinetic study. The physicochemical study of LSH revealed its bioenergy capability to create renewable fuel and valued compounds. Further, isoconversional models such as OFW, KAS, TM, STM, and VZM yielded average activation energy of 164, 154.35, 154.63, 154.61, and 141.93 kJ/mol. The master plot and thermodynamic study of LSH confirmed that the pyrolysis process passed through multifaceted reaction mechanisms.

AB - The current investigation demonstrated the physicochemical study, pyrolysis performance, and kinetic study of Lagerstroemia speciosa seed hull (LSH) biomass in a thermogravimetric analyzer under an inert ambiance. LSH sample was characterized by proximate study, elemental study, calorific value, biochemical analysis, and thermal stability study, whereas; isoconversional models such as Ozawa-Flynn-Wall (OFW), Kissinger-Akahira-Sunose (KAS), Vyazovkin (VZM), Tang method (TM), and Starink method (STM) were used for performing the kinetic study. The physicochemical study of LSH revealed its bioenergy capability to create renewable fuel and valued compounds. Further, isoconversional models such as OFW, KAS, TM, STM, and VZM yielded average activation energy of 164, 154.35, 154.63, 154.61, and 141.93 kJ/mol. The master plot and thermodynamic study of LSH confirmed that the pyrolysis process passed through multifaceted reaction mechanisms.

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DO - 10.1016/j.biteb.2021.100858

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SN - 2589-014X

VL - 16

JO - Bioresource Technology Reports

JF - Bioresource Technology Reports

M1 - 100858

ER -

Studies of physicochemical characterization and pyrolysis behavior of low-value waste biomass using Thermogravimetric analyzer: evaluation of kinetic and thermodynamic parameters

Abstract

UN SDGs

All Science Journal Classification (ASJC) codes

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