Studies on the Solid Oxide Cell Perovskite Electrode Materials for Soot Oxidation Activity

Chaitra S. Shenoy; Sunaina S. Patil; P. Govardhan; Atmuri Shourya; Hari Prasad Dasari; M. B. Saidutta; Harshini Dasari

doi:10.1007/s40825-019-00144-z

Studies on the Solid Oxide Cell Perovskite Electrode Materials for Soot Oxidation Activity

Chaitra S. Shenoy, Sunaina S. Patil, P. Govardhan, Atmuri Shourya, Hari Prasad Dasari, M. B. Saidutta, Harshini Dasari

Department of Chemical Engineering, Manipal Institute of Technology, Manipal

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

Solid oxide cell (SOC) perovskite electrode materials (BSCF (Ba_0.5Sr_0.5Co_0.8Fe_0.2O_3-δ), LSCF (La_0.6Sr_0.4Co_0.2Fe_0.8O_3-δ) and LSCM (La_0.75Sr_0.25Cr_0.5Mn_0.5O_3-δ)) were synthesised using microwave-assisted reverse-strike co-precipitation method and tested for soot oxidation activity. The calcined perovskite materials were characterized using FT-IR, XRD, SEM and BSE, BET and BJH and XPS analysis. The mean activation energy for soot oxidation was calculated from Ozawa plots at various heating rates (5, 10, 15 and 20 K/min) at different levels of soot conversions (T₁₀ to T₉₀) for BSCF, LSCM and LSCF perovskite materials and was around 133 ± 11.5, 138 ± 9.9 and 152 ± 7.2 kJ/mol, respectively. Irrespective of the heating rates, BSCF material showed the lowest T₅₀ temperature than compared to other samples, and it is correlated to the presence of Fe₃O₄ as a secondary phase.

Original language	English
Pages (from-to)	342-352
Number of pages	11
Journal	Emission Control Science and Technology
Volume	5
Issue number	4
DOIs	https://doi.org/10.1007/s40825-019-00144-z
Publication status	Published - 15-12-2019

All Science Journal Classification (ASJC) codes

Automotive Engineering
Pollution
Management, Monitoring, Policy and Law
Health, Toxicology and Mutagenesis

Access to Document

10.1007/s40825-019-00144-z

Cite this

@article{fb69d17689584b01b325e788667be878,

title = "Studies on the Solid Oxide Cell Perovskite Electrode Materials for Soot Oxidation Activity",

abstract = "Solid oxide cell (SOC) perovskite electrode materials (BSCF (Ba0.5Sr0.5Co0.8Fe0.2O3-δ), LSCF (La0.6Sr0.4Co0.2Fe0.8O3-δ) and LSCM (La0.75Sr0.25Cr0.5Mn0.5O3-δ)) were synthesised using microwave-assisted reverse-strike co-precipitation method and tested for soot oxidation activity. The calcined perovskite materials were characterized using FT-IR, XRD, SEM and BSE, BET and BJH and XPS analysis. The mean activation energy for soot oxidation was calculated from Ozawa plots at various heating rates (5, 10, 15 and 20 K/min) at different levels of soot conversions (T10 to T90) for BSCF, LSCM and LSCF perovskite materials and was around 133 ± 11.5, 138 ± 9.9 and 152 ± 7.2 kJ/mol, respectively. Irrespective of the heating rates, BSCF material showed the lowest T50 temperature than compared to other samples, and it is correlated to the presence of Fe3O4 as a secondary phase.",

author = "Shenoy, {Chaitra S.} and Patil, {Sunaina S.} and P. Govardhan and Atmuri Shourya and Dasari, {Hari Prasad} and Saidutta, {M. B.} and Harshini Dasari",

year = "2019",

month = dec,

day = "15",

doi = "10.1007/s40825-019-00144-z",

language = "English",

volume = "5",

pages = "342--352",

journal = "Emission Control Science and Technology",

issn = "2199-3629",

publisher = "Springer International Publishing AG",

number = "4",

}

TY - JOUR

T1 - Studies on the Solid Oxide Cell Perovskite Electrode Materials for Soot Oxidation Activity

AU - Shenoy, Chaitra S.

AU - Patil, Sunaina S.

AU - Govardhan, P.

AU - Shourya, Atmuri

AU - Dasari, Hari Prasad

AU - Saidutta, M. B.

AU - Dasari, Harshini

PY - 2019/12/15

Y1 - 2019/12/15

N2 - Solid oxide cell (SOC) perovskite electrode materials (BSCF (Ba0.5Sr0.5Co0.8Fe0.2O3-δ), LSCF (La0.6Sr0.4Co0.2Fe0.8O3-δ) and LSCM (La0.75Sr0.25Cr0.5Mn0.5O3-δ)) were synthesised using microwave-assisted reverse-strike co-precipitation method and tested for soot oxidation activity. The calcined perovskite materials were characterized using FT-IR, XRD, SEM and BSE, BET and BJH and XPS analysis. The mean activation energy for soot oxidation was calculated from Ozawa plots at various heating rates (5, 10, 15 and 20 K/min) at different levels of soot conversions (T10 to T90) for BSCF, LSCM and LSCF perovskite materials and was around 133 ± 11.5, 138 ± 9.9 and 152 ± 7.2 kJ/mol, respectively. Irrespective of the heating rates, BSCF material showed the lowest T50 temperature than compared to other samples, and it is correlated to the presence of Fe3O4 as a secondary phase.

AB - Solid oxide cell (SOC) perovskite electrode materials (BSCF (Ba0.5Sr0.5Co0.8Fe0.2O3-δ), LSCF (La0.6Sr0.4Co0.2Fe0.8O3-δ) and LSCM (La0.75Sr0.25Cr0.5Mn0.5O3-δ)) were synthesised using microwave-assisted reverse-strike co-precipitation method and tested for soot oxidation activity. The calcined perovskite materials were characterized using FT-IR, XRD, SEM and BSE, BET and BJH and XPS analysis. The mean activation energy for soot oxidation was calculated from Ozawa plots at various heating rates (5, 10, 15 and 20 K/min) at different levels of soot conversions (T10 to T90) for BSCF, LSCM and LSCF perovskite materials and was around 133 ± 11.5, 138 ± 9.9 and 152 ± 7.2 kJ/mol, respectively. Irrespective of the heating rates, BSCF material showed the lowest T50 temperature than compared to other samples, and it is correlated to the presence of Fe3O4 as a secondary phase.

UR - http://www.scopus.com/inward/record.url?scp=85075372855&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85075372855&partnerID=8YFLogxK

U2 - 10.1007/s40825-019-00144-z

DO - 10.1007/s40825-019-00144-z

M3 - Article

AN - SCOPUS:85075372855

SN - 2199-3629

VL - 5

SP - 342

EP - 352

JO - Emission Control Science and Technology

JF - Emission Control Science and Technology

IS - 4

ER -

Studies on the Solid Oxide Cell Perovskite Electrode Materials for Soot Oxidation Activity

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this