Syntheses and non-covalent interactions of naphthalene-bearing Schiff base complexes of Zn(II), Co(III), Cu(II) and V(IV): Selective detection of Zn(II)

Barnali Naskar; Ritwik Modak; Dilip K. Maiti; Sushil Kumar Mandal; Jayanta Kumar Biswas; Tapan Kumar Mondal; Sanchita Goswami

doi:10.1016/j.poly.2016.07.018

Syntheses and non-covalent interactions of naphthalene-bearing Schiff base complexes of Zn(II), Co(III), Cu(II) and V(IV): Selective detection of Zn(II)

Barnali Naskar, Ritwik Modak, Dilip K. Maiti, Sushil Kumar Mandal, Jayanta Kumar Biswas, Tapan Kumar Mondal, Sanchita Goswami^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

A new Schiff base ligand, 1-[(2-pyridin-2-yl-ethylimino)-methyl]-naphthalen-2-ol, (HPEMN) has been synthesized equipped with naphthalene and pyridine backbone, to study the interplay of various non-covalent interactions. Experiments have been carried out to investigate the outcome of combinations of HPEMN and ZnCl₂(1), ZnBr₂(2), ZnI₂(3), Zn(NO₃)₂·6H₂O (4), Co(ClO₄)₂·6H₂O (5), Cu(ClO₄)₂·6H₂O (6) and VO(acac)₂(7). The prevalent non-covalent interactions described here include naphthalene–naphthalene (for 1, 2, 3 and 5) and pyridine–pyridine π–π stacking (for 4) interactions, nitrate anion⋯π interaction (for 4) and hydrogen bonding (for 6). HPEMN is able to sense Zn(II) selectively and this phenomenon was further demonstrated by the results of fluorescence studies in H₂O/acetonitrile (8:2, v/v) HEPES buffer (pH = 7.4) solution and human lung cancer cell lines.

Original language	English
Pages (from-to)	834-846
Number of pages	13
Journal	Polyhedron
Volume	117
DOIs	https://doi.org/10.1016/j.poly.2016.07.018
Publication status	Published - 2016

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1016/j.poly.2016.07.018

Cite this

@article{ae46d5f45a854149a14a46603e07345d,

title = "Syntheses and non-covalent interactions of naphthalene-bearing Schiff base complexes of Zn(II), Co(III), Cu(II) and V(IV): Selective detection of Zn(II)",

abstract = "A new Schiff base ligand, 1-[(2-pyridin-2-yl-ethylimino)-methyl]-naphthalen-2-ol, (HPEMN) has been synthesized equipped with naphthalene and pyridine backbone, to study the interplay of various non-covalent interactions. Experiments have been carried out to investigate the outcome of combinations of HPEMN and ZnCl2(1), ZnBr2(2), ZnI2(3), Zn(NO3)2·6H2O (4), Co(ClO4)2·6H2O (5), Cu(ClO4)2·6H2O (6) and VO(acac)2(7). The prevalent non-covalent interactions described here include naphthalene–naphthalene (for 1, 2, 3 and 5) and pyridine–pyridine π–π stacking (for 4) interactions, nitrate anion⋯π interaction (for 4) and hydrogen bonding (for 6). HPEMN is able to sense Zn(II) selectively and this phenomenon was further demonstrated by the results of fluorescence studies in H2O/acetonitrile (8:2, v/v) HEPES buffer (pH = 7.4) solution and human lung cancer cell lines.",

author = "Barnali Naskar and Ritwik Modak and Maiti, {Dilip K.} and {Kumar Mandal}, Sushil and {Kumar Biswas}, Jayanta and {Kumar Mondal}, Tapan and Sanchita Goswami",

note = "Publisher Copyright: {\textcopyright} 2016 Elsevier Ltd",

year = "2016",

doi = "10.1016/j.poly.2016.07.018",

language = "English",

volume = "117",

pages = "834--846",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Limited",

}

TY - JOUR

T1 - Syntheses and non-covalent interactions of naphthalene-bearing Schiff base complexes of Zn(II), Co(III), Cu(II) and V(IV)

T2 - Selective detection of Zn(II)

AU - Naskar, Barnali

AU - Modak, Ritwik

AU - Maiti, Dilip K.

AU - Kumar Mandal, Sushil

AU - Kumar Biswas, Jayanta

AU - Kumar Mondal, Tapan

AU - Goswami, Sanchita

PY - 2016

Y1 - 2016

N2 - A new Schiff base ligand, 1-[(2-pyridin-2-yl-ethylimino)-methyl]-naphthalen-2-ol, (HPEMN) has been synthesized equipped with naphthalene and pyridine backbone, to study the interplay of various non-covalent interactions. Experiments have been carried out to investigate the outcome of combinations of HPEMN and ZnCl2(1), ZnBr2(2), ZnI2(3), Zn(NO3)2·6H2O (4), Co(ClO4)2·6H2O (5), Cu(ClO4)2·6H2O (6) and VO(acac)2(7). The prevalent non-covalent interactions described here include naphthalene–naphthalene (for 1, 2, 3 and 5) and pyridine–pyridine π–π stacking (for 4) interactions, nitrate anion⋯π interaction (for 4) and hydrogen bonding (for 6). HPEMN is able to sense Zn(II) selectively and this phenomenon was further demonstrated by the results of fluorescence studies in H2O/acetonitrile (8:2, v/v) HEPES buffer (pH = 7.4) solution and human lung cancer cell lines.

AB - A new Schiff base ligand, 1-[(2-pyridin-2-yl-ethylimino)-methyl]-naphthalen-2-ol, (HPEMN) has been synthesized equipped with naphthalene and pyridine backbone, to study the interplay of various non-covalent interactions. Experiments have been carried out to investigate the outcome of combinations of HPEMN and ZnCl2(1), ZnBr2(2), ZnI2(3), Zn(NO3)2·6H2O (4), Co(ClO4)2·6H2O (5), Cu(ClO4)2·6H2O (6) and VO(acac)2(7). The prevalent non-covalent interactions described here include naphthalene–naphthalene (for 1, 2, 3 and 5) and pyridine–pyridine π–π stacking (for 4) interactions, nitrate anion⋯π interaction (for 4) and hydrogen bonding (for 6). HPEMN is able to sense Zn(II) selectively and this phenomenon was further demonstrated by the results of fluorescence studies in H2O/acetonitrile (8:2, v/v) HEPES buffer (pH = 7.4) solution and human lung cancer cell lines.

UR - http://www.scopus.com/inward/record.url?scp=84982129847&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84982129847&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2016.07.018

DO - 10.1016/j.poly.2016.07.018

M3 - Article

AN - SCOPUS:84982129847

SN - 0277-5387

VL - 117

SP - 834

EP - 846

JO - Polyhedron

JF - Polyhedron

ER -

Syntheses and non-covalent interactions of naphthalene-bearing Schiff base complexes of Zn(II), Co(III), Cu(II) and V(IV): Selective detection of Zn(II)

Abstract

All Science Journal Classification (ASJC) codes

UN SDGs

Access to Document

Other files and links

Fingerprint

Cite this