Synthesis and characterization of novel chiral imidazolium and pyridinium ionic liquids derived from tartaric acid and 2-oxazolidinone

Sagar P. Nehate; Himanshu M. Godbole; Girij P. Singh; Jessy E. Mathew; Gautham G. Shenoy

doi:10.1080/00397911.2019.1591455

Synthesis and characterization of novel chiral imidazolium and pyridinium ionic liquids derived from tartaric acid and 2-oxazolidinone

Sagar P. Nehate, Himanshu M. Godbole, Girij P. Singh, Jessy E. Mathew, Gautham G. Shenoy

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Novel chiral imidazolium and pyridinium ionic liquids based on tartaric acid and 2-oxazolidinone were designed. Symmetrical dicationic ionic liquids based on tartaric acid have been synthesized and characterized. These chiral ionic liquids were designed by employing very short and simple methods. Incorporation of alkyl halide over tartaric acid and 2-oxazolidinone is an important step. N-methyl imidazole and pyridine were used for preparation of quaternary salts. These ionic liquids have been evaluated for the asymmetric sulfide oxidation. Chiral ionic liquids based on tartaric acid showed superior chiral inducing property as compare to 2-oxazolidinone based chiral ionic liquids.

Original language	English
Pages (from-to)	1173-1180
Number of pages	8
Journal	Synthetic Communications
Volume	49
Issue number	9
DOIs	https://doi.org/10.1080/00397911.2019.1591455
Publication status	Published - 03-05-2019

All Science Journal Classification (ASJC) codes

Organic Chemistry

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10.1080/00397911.2019.1591455

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title = "Synthesis and characterization of novel chiral imidazolium and pyridinium ionic liquids derived from tartaric acid and 2-oxazolidinone",

abstract = "Novel chiral imidazolium and pyridinium ionic liquids based on tartaric acid and 2-oxazolidinone were designed. Symmetrical dicationic ionic liquids based on tartaric acid have been synthesized and characterized. These chiral ionic liquids were designed by employing very short and simple methods. Incorporation of alkyl halide over tartaric acid and 2-oxazolidinone is an important step. N-methyl imidazole and pyridine were used for preparation of quaternary salts. These ionic liquids have been evaluated for the asymmetric sulfide oxidation. Chiral ionic liquids based on tartaric acid showed superior chiral inducing property as compare to 2-oxazolidinone based chiral ionic liquids.",

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AU - Nehate, Sagar P.

AU - Godbole, Himanshu M.

AU - Singh, Girij P.

AU - Mathew, Jessy E.

AU - Shenoy, Gautham G.

PY - 2019/5/3

Y1 - 2019/5/3

N2 - Novel chiral imidazolium and pyridinium ionic liquids based on tartaric acid and 2-oxazolidinone were designed. Symmetrical dicationic ionic liquids based on tartaric acid have been synthesized and characterized. These chiral ionic liquids were designed by employing very short and simple methods. Incorporation of alkyl halide over tartaric acid and 2-oxazolidinone is an important step. N-methyl imidazole and pyridine were used for preparation of quaternary salts. These ionic liquids have been evaluated for the asymmetric sulfide oxidation. Chiral ionic liquids based on tartaric acid showed superior chiral inducing property as compare to 2-oxazolidinone based chiral ionic liquids.

AB - Novel chiral imidazolium and pyridinium ionic liquids based on tartaric acid and 2-oxazolidinone were designed. Symmetrical dicationic ionic liquids based on tartaric acid have been synthesized and characterized. These chiral ionic liquids were designed by employing very short and simple methods. Incorporation of alkyl halide over tartaric acid and 2-oxazolidinone is an important step. N-methyl imidazole and pyridine were used for preparation of quaternary salts. These ionic liquids have been evaluated for the asymmetric sulfide oxidation. Chiral ionic liquids based on tartaric acid showed superior chiral inducing property as compare to 2-oxazolidinone based chiral ionic liquids.

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Synthesis and characterization of novel chiral imidazolium and pyridinium ionic liquids derived from tartaric acid and 2-oxazolidinone

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