Synthesis and Characterization of the New Clusters Ru4(CO)11(μ4-Te)2, Ru3(CO)6(PPh3)3(μ3-Te)2, Ru4(CO)10(PPh3)(μ4-Te)2, and Ru4(CO)9(μ-Ph2PCH2PPh2)(μ4Te)2

Pradeep Mathur; B. H.S. Thimmappa; Arnold L. Rheingold

doi:10.1021/ic00348a015

Synthesis and Characterization of the New Clusters Ru₄(CO)₁₁(μ₄-Te)₂, Ru₃(CO)₆(PPh₃)₃(μ₃-Te)₂, Ru₄(CO)₁₀(PPh₃)(μ₄-Te)₂, and Ru₄(CO)₉(μ-Ph₂PCH₂PPh₂)(μ₄Te)₂

Pradeep Mathur
, B. H.S. Thimmappa
, Arnold L. Rheingold

Research output: Contribution to journal › Article › peer-review

62 Citations (Scopus)

Abstract

The compound Ru₄(CO)₁₁(μ₄-Te)₂(1) has been prepared by refluxing a benzene solution containing Fe₃(CO)₉(μ₃-Te)₂and Ru₃(CO)₁₂. The compounds Ru₃(CO)₆(PPh₃)₃(μ₃-Te)₂(2) and Ru₄(CO)₁₀(PPh₃)(μ₄-Te)₂(3) were obtained from the room-temperature reaction of 1 with PPh₃. Similarly, Ru₄(CO)₉(μ-Ph₂PCH₂PPh₂)(μ₄-Te)₂(4) was obtained from the reaction of 1 with Ph₂PCH₂PPh₂at room temperature. The structure of 1–4 were established by single-crystal X-ray diffraction analysis. Crystal data: 1, orthorhombic, Pccn, a = 6.924 (2) Å, b = 16.289 (6) Å, c = 18.054 (6) Å, V = 2036 (1) Å³, Z = 4, R(F) = 4.16%; 2, monoclinic, P2₁/n, a = 10.539 (4) Å, b = 27.39 (1) Å, c = 20.415 (7) Å, β = 94.96 (3)°, V= 5870 (4) Å³, Z = 4, R(F) = 4.96%; 3, orthorhombic, Pbca, a = 19.070 (5) Å, b = 18.157 (4) Å, c = 19.272 (5) Å, V= 6673 (3) Å³, Z = 8, R(F) = 3.65%; 4, triclinic, P1, a = 13.255 (3) Å, b = 17.610 (5) Å, c = 19.189 (5) Å, α = 65.39 (2)°, β = 78.25 (2)°, γ = 84.13 (2)°, V = 3986 (2) Å³, Z = 4, R(F) = 2.97%.

Original language	English
Pages (from-to)	4658-4665
Number of pages	8
Journal	Inorganic Chemistry
Volume	29
Issue number	23
DOIs	https://doi.org/10.1021/ic00348a015
Publication status	Published - 01-01-1990

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic00348a015

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@article{0dc4ef36ee7943c2ace7ecd4684954d1,

title = "Synthesis and Characterization of the New Clusters Ru4(CO)11(μ4-Te)2, Ru3(CO)6(PPh3)3(μ3-Te)2, Ru4(CO)10(PPh3)(μ4-Te)2, and Ru4(CO)9(μ-Ph2PCH2PPh2)(μ4Te)2",

abstract = "The compound Ru4(CO)11(μ4-Te)2(1) has been prepared by refluxing a benzene solution containing Fe3(CO)9(μ3-Te)2and Ru3(CO)12. The compounds Ru3(CO)6(PPh3)3(μ3-Te)2(2) and Ru4(CO)10(PPh3)(μ4-Te)2(3) were obtained from the room-temperature reaction of 1 with PPh3. Similarly, Ru4(CO)9(μ-Ph2PCH2PPh2)(μ4-Te)2(4) was obtained from the reaction of 1 with Ph2PCH2PPh2at room temperature. The structure of 1–4 were established by single-crystal X-ray diffraction analysis. Crystal data: 1, orthorhombic, Pccn, a = 6.924 (2) {\AA}, b = 16.289 (6) {\AA}, c = 18.054 (6) {\AA}, V = 2036 (1) {\AA}3, Z = 4, R(F) = 4.16\%; 2, monoclinic, P21/n, a = 10.539 (4) {\AA}, b = 27.39 (1) {\AA}, c = 20.415 (7) {\AA}, β = 94.96 (3)°, V= 5870 (4) {\AA}3, Z = 4, R(F) = 4.96\%; 3, orthorhombic, Pbca, a = 19.070 (5) {\AA}, b = 18.157 (4) {\AA}, c = 19.272 (5) {\AA}, V= 6673 (3) {\AA}3, Z = 8, R(F) = 3.65\%; 4, triclinic, P1, a = 13.255 (3) {\AA}, b = 17.610 (5) {\AA}, c = 19.189 (5) {\AA}, α = 65.39 (2)°, β = 78.25 (2)°, γ = 84.13 (2)°, V = 3986 (2) {\AA}3, Z = 4, R(F) = 2.97\%.",

author = "Pradeep Mathur and Thimmappa, \{B. H.S.\} and Rheingold, \{Arnold L.\}",

year = "1990",

month = jan,

day = "1",

doi = "10.1021/ic00348a015",

language = "English",

volume = "29",

pages = "4658--4665",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "23",

}

TY - JOUR

T1 - Synthesis and Characterization of the New Clusters Ru4(CO)11(μ4-Te)2, Ru3(CO)6(PPh3)3(μ3-Te)2, Ru4(CO)10(PPh3)(μ4-Te)2, and Ru4(CO)9(μ-Ph2PCH2PPh2)(μ4Te)2

AU - Mathur, Pradeep

AU - Thimmappa, B. H.S.

AU - Rheingold, Arnold L.

PY - 1990/1/1

Y1 - 1990/1/1

N2 - The compound Ru4(CO)11(μ4-Te)2(1) has been prepared by refluxing a benzene solution containing Fe3(CO)9(μ3-Te)2and Ru3(CO)12. The compounds Ru3(CO)6(PPh3)3(μ3-Te)2(2) and Ru4(CO)10(PPh3)(μ4-Te)2(3) were obtained from the room-temperature reaction of 1 with PPh3. Similarly, Ru4(CO)9(μ-Ph2PCH2PPh2)(μ4-Te)2(4) was obtained from the reaction of 1 with Ph2PCH2PPh2at room temperature. The structure of 1–4 were established by single-crystal X-ray diffraction analysis. Crystal data: 1, orthorhombic, Pccn, a = 6.924 (2) Å, b = 16.289 (6) Å, c = 18.054 (6) Å, V = 2036 (1) Å3, Z = 4, R(F) = 4.16%; 2, monoclinic, P21/n, a = 10.539 (4) Å, b = 27.39 (1) Å, c = 20.415 (7) Å, β = 94.96 (3)°, V= 5870 (4) Å3, Z = 4, R(F) = 4.96%; 3, orthorhombic, Pbca, a = 19.070 (5) Å, b = 18.157 (4) Å, c = 19.272 (5) Å, V= 6673 (3) Å3, Z = 8, R(F) = 3.65%; 4, triclinic, P1, a = 13.255 (3) Å, b = 17.610 (5) Å, c = 19.189 (5) Å, α = 65.39 (2)°, β = 78.25 (2)°, γ = 84.13 (2)°, V = 3986 (2) Å3, Z = 4, R(F) = 2.97%.

AB - The compound Ru4(CO)11(μ4-Te)2(1) has been prepared by refluxing a benzene solution containing Fe3(CO)9(μ3-Te)2and Ru3(CO)12. The compounds Ru3(CO)6(PPh3)3(μ3-Te)2(2) and Ru4(CO)10(PPh3)(μ4-Te)2(3) were obtained from the room-temperature reaction of 1 with PPh3. Similarly, Ru4(CO)9(μ-Ph2PCH2PPh2)(μ4-Te)2(4) was obtained from the reaction of 1 with Ph2PCH2PPh2at room temperature. The structure of 1–4 were established by single-crystal X-ray diffraction analysis. Crystal data: 1, orthorhombic, Pccn, a = 6.924 (2) Å, b = 16.289 (6) Å, c = 18.054 (6) Å, V = 2036 (1) Å3, Z = 4, R(F) = 4.16%; 2, monoclinic, P21/n, a = 10.539 (4) Å, b = 27.39 (1) Å, c = 20.415 (7) Å, β = 94.96 (3)°, V= 5870 (4) Å3, Z = 4, R(F) = 4.96%; 3, orthorhombic, Pbca, a = 19.070 (5) Å, b = 18.157 (4) Å, c = 19.272 (5) Å, V= 6673 (3) Å3, Z = 8, R(F) = 3.65%; 4, triclinic, P1, a = 13.255 (3) Å, b = 17.610 (5) Å, c = 19.189 (5) Å, α = 65.39 (2)°, β = 78.25 (2)°, γ = 84.13 (2)°, V = 3986 (2) Å3, Z = 4, R(F) = 2.97%.

UR - https://www.scopus.com/pages/publications/0000970886

UR - https://www.scopus.com/pages/publications/0000970886#tab=citedBy

U2 - 10.1021/ic00348a015

DO - 10.1021/ic00348a015

M3 - Article

AN - SCOPUS:0000970886

SN - 0020-1669

VL - 29

SP - 4658

EP - 4665

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 23

ER -

Synthesis and Characterization of the New Clusters Ru₄(CO)₁₁(μ₄-Te)₂, Ru₃(CO)₆(PPh₃)₃(μ₃-Te)₂, Ru₄(CO)₁₀(PPh₃)(μ₄-Te)₂, and Ru₄(CO)₉(μ-Ph₂PCH₂PPh₂)(μ₄Te)₂

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