Abstract
A new strategy for the total synthesis of (±)-seychellene 1 is described. The key step is an intramolecular Michael addition involving a 6-exo cyclisation with a vinyl radical derived from the acetylenic compound 11, obtained from the bicyclo[2.2.2]octene adduct 5 to the tricyclic intermediates 14 and 15.
| Original language | English |
|---|---|
| Pages (from-to) | 2813-2816 |
| Number of pages | 4 |
| Journal | Journal of the Chemical Society, Perkin Transactions 1 |
| Issue number | 22 |
| Publication status | Published - 1993 |
All Science Journal Classification (ASJC) codes
- General Chemistry
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