TY - JOUR
T1 - Synthesis, spectral, magnetic susceptibility and antifungal studies on symmetrically substituted metal (II) octafuryl methanimine phthalocyanine
AU - Fasiulla, null
AU - Venugopala Reddy, K. R.
AU - Moinuddin Khan, M. H.
AU - Keshavayya, J.
PY - 2011/5/12
Y1 - 2011/5/12
N2 - Novel phthalocyanines with eight octa-1-(3-furyl) methanimine phthalocyanine, (CufurylImPcO) groups. Present paper discuss the synthesis and characterizatiopn of metal (II) 1, 3, 8, 10, 15, 17, 22, 24- octa-1-(3-furyl) methanimine phthalocyanines (M-furylImPcO) (M = Cu, Co, Ni, Zn) by an efficient simple method. Octaamino metal (II) phthalocyanines were synthesized by the reduction of the corresponding nitro phthalocyanines. The dark green octa-1-(3-furyl)methanimine phthalocyanine derivatives were characterized by elemental analysis, magnetic susceptibility, electronic, IR and powder X-ray diffraction studies to check the purity, structural integrity and crystalline properties of the complexes. Magnetic susceptibility studies on Co (II) and Cu (II) octa-1-(3-furyl) methanimine phthalocyanine complexes exhibit a variation of the magnetic moments as a function of field strength indicating the presence of inter molecular co-operative effect. The complexes were screened for antifungal activity.
AB - Novel phthalocyanines with eight octa-1-(3-furyl) methanimine phthalocyanine, (CufurylImPcO) groups. Present paper discuss the synthesis and characterizatiopn of metal (II) 1, 3, 8, 10, 15, 17, 22, 24- octa-1-(3-furyl) methanimine phthalocyanines (M-furylImPcO) (M = Cu, Co, Ni, Zn) by an efficient simple method. Octaamino metal (II) phthalocyanines were synthesized by the reduction of the corresponding nitro phthalocyanines. The dark green octa-1-(3-furyl)methanimine phthalocyanine derivatives were characterized by elemental analysis, magnetic susceptibility, electronic, IR and powder X-ray diffraction studies to check the purity, structural integrity and crystalline properties of the complexes. Magnetic susceptibility studies on Co (II) and Cu (II) octa-1-(3-furyl) methanimine phthalocyanine complexes exhibit a variation of the magnetic moments as a function of field strength indicating the presence of inter molecular co-operative effect. The complexes were screened for antifungal activity.
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M3 - Article
AN - SCOPUS:79955718971
SN - 0975-413X
VL - 3
SP - 392
EP - 403
JO - Der Pharma Chemica
JF - Der Pharma Chemica
IS - 2
ER -