The effect of solvent induced crystallinity of polymer layer on poly(3-hexylthiophene)/C70 bilayer solar cells

Dhananjaya Kekuda; Hao Shing Lin; Meng Chyi Wu; Jen Shein Huang; Kuo Chuan Ho; Chih Wei Chu

doi:10.1016/j.solmat.2010.05.055

The effect of solvent induced crystallinity of polymer layer on poly(3-hexylthiophene)/C₇₀ bilayer solar cells

Dhananjaya Kekuda
, Hao Shing Lin
, Meng Chyi Wu
, Jen Shein Huang
, Kuo Chuan Ho
, Chih Wei Chu^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

A bilayer polymer solar cell is demonstrated with the device configuration ITO/PEDOT:PSS/poly(3-hexylthiophene)/C₇₀/Al. In this article, we highlight the importance of polymer surface morphology, its crystallinity and mobility on device output parameters. The solvent used for polymer processing plays a major role in deciding these parameters and it was observed that high boiling point solvents are desirable for achieving large surface roughness of the polymer layer, which in turn provide more interface area in the bilayer device structure. Due to the increased interface area for exciton dissociation, these bilayer devices resulted in a maximum power conversion efficiency of 3.65% under one sun radiation.

Original language	English
Pages (from-to)	419-422
Number of pages	4
Journal	Solar Energy Materials and Solar Cells
Volume	95
Issue number	2
DOIs	https://doi.org/10.1016/j.solmat.2010.05.055
Publication status	Published - 01-02-2011

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Renewable Energy, Sustainability and the Environment
Surfaces, Coatings and Films

Access to Document

10.1016/j.solmat.2010.05.055

Cite this

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title = "The effect of solvent induced crystallinity of polymer layer on poly(3-hexylthiophene)/C70 bilayer solar cells",

abstract = "A bilayer polymer solar cell is demonstrated with the device configuration ITO/PEDOT:PSS/poly(3-hexylthiophene)/C70/Al. In this article, we highlight the importance of polymer surface morphology, its crystallinity and mobility on device output parameters. The solvent used for polymer processing plays a major role in deciding these parameters and it was observed that high boiling point solvents are desirable for achieving large surface roughness of the polymer layer, which in turn provide more interface area in the bilayer device structure. Due to the increased interface area for exciton dissociation, these bilayer devices resulted in a maximum power conversion efficiency of 3.65\% under one sun radiation.",

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AU - Lin, Hao Shing

AU - Chyi Wu, Meng

AU - Huang, Jen Shein

AU - Ho, Kuo Chuan

AU - Chu, Chih Wei

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AB - A bilayer polymer solar cell is demonstrated with the device configuration ITO/PEDOT:PSS/poly(3-hexylthiophene)/C70/Al. In this article, we highlight the importance of polymer surface morphology, its crystallinity and mobility on device output parameters. The solvent used for polymer processing plays a major role in deciding these parameters and it was observed that high boiling point solvents are desirable for achieving large surface roughness of the polymer layer, which in turn provide more interface area in the bilayer device structure. Due to the increased interface area for exciton dissociation, these bilayer devices resulted in a maximum power conversion efficiency of 3.65% under one sun radiation.

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