TY - JOUR
T1 - Thermocatalytic conversion of non-edible Neem seeds towards clean fuel and chemicals
AU - Mishra, Ranjeet Kumar
AU - Mohanty, Kaustubha
N1 - Publisher Copyright:
© 2018 Elsevier B.V.
PY - 2018/9
Y1 - 2018/9
N2 - In this work, a non-edible seed Neem (Azadirachta indica) was used to find out it's potential to produce fuels and chemicals using thermo-catalytic pyrolysis. The physiochemical characterization confirmed the seed's bioenergy potential. Thermal and catalytic pyrolysis were carried out at optimum conditions (500 °C temperature, 80 °C min−1 heating rate, 0.5 mm particle size and 80 mL min−1 nitrogen gas flow rate) which produced maximum liquid yield (49.53 wt. % at thermal, 54.06 wt. % and 52.08 wt. % for K2CO3 and Zeolite respectively at Biomass/Catalyst ratio 8:1). The comparative study of thermal and catalytic pyrolytic liquid confirmed that the yield as well as fuel properties of pyrolytic liquid were enhanced with the use of catalysts. It was also noticed that the energy content of gases increased with increasing pyrolysis temperature. Further, with increase in pyrolysis temperature, the amounts of hydrogen and hydrocarbons increased significantly, but at the same time, the formation of carbon dioxide was reduced.
AB - In this work, a non-edible seed Neem (Azadirachta indica) was used to find out it's potential to produce fuels and chemicals using thermo-catalytic pyrolysis. The physiochemical characterization confirmed the seed's bioenergy potential. Thermal and catalytic pyrolysis were carried out at optimum conditions (500 °C temperature, 80 °C min−1 heating rate, 0.5 mm particle size and 80 mL min−1 nitrogen gas flow rate) which produced maximum liquid yield (49.53 wt. % at thermal, 54.06 wt. % and 52.08 wt. % for K2CO3 and Zeolite respectively at Biomass/Catalyst ratio 8:1). The comparative study of thermal and catalytic pyrolytic liquid confirmed that the yield as well as fuel properties of pyrolytic liquid were enhanced with the use of catalysts. It was also noticed that the energy content of gases increased with increasing pyrolysis temperature. Further, with increase in pyrolysis temperature, the amounts of hydrogen and hydrocarbons increased significantly, but at the same time, the formation of carbon dioxide was reduced.
UR - https://www.scopus.com/pages/publications/85048596959
UR - https://www.scopus.com/inward/citedby.url?scp=85048596959&partnerID=8YFLogxK
U2 - 10.1016/j.jaap.2018.05.013
DO - 10.1016/j.jaap.2018.05.013
M3 - Article
AN - SCOPUS:85048596959
SN - 0165-2370
VL - 134
SP - 83
EP - 92
JO - Journal of Analytical and Applied Pyrolysis
JF - Journal of Analytical and Applied Pyrolysis
ER -