Titanium (III) reduction of dimethylglyoxime: Electrochemical and kinetic studies

M. P. Yashoda; Padmalatha; B. S. Sherigara; P. V. Nayak

Titanium (III) reduction of dimethylglyoxime: Electrochemical and kinetic studies

M. P. Yashoda
, Padmalatha
, B. S. Sherigara^*
, P. V. Nayak

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Titanium (III) mediated electroreduction of dimethyl glyoxime has been carried out in aqueous sulphuric acid medium and the reduction product has been isolated and characterised. The kinetic investigations have been carried out under stoichiometric and non-stoichiometric conditions at 306K. It has been found that the reaction follows overall second order kinetics, first order each in [Ti(III)] and [DMG] and fractional order in sulphuric acid. The effect of varying concentrations of Ti(III), DMG, H₂SO₄, ionic strength, and solvent composition has been studied. Effect of temperature has also been studied and activation parameters have been computed from Arrhenius and Eyring plots.

Original language	English
Pages (from-to)	176-179
Number of pages	4
Journal	Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry
Volume	38
Issue number	2
Publication status	Published - 02-1999

All Science Journal Classification (ASJC) codes

General Chemistry

Cite this

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title = "Titanium (III) reduction of dimethylglyoxime: Electrochemical and kinetic studies",

abstract = "Titanium (III) mediated electroreduction of dimethyl glyoxime has been carried out in aqueous sulphuric acid medium and the reduction product has been isolated and characterised. The kinetic investigations have been carried out under stoichiometric and non-stoichiometric conditions at 306K. It has been found that the reaction follows overall second order kinetics, first order each in [Ti(III)] and [DMG] and fractional order in sulphuric acid. The effect of varying concentrations of Ti(III), DMG, H2SO4, ionic strength, and solvent composition has been studied. Effect of temperature has also been studied and activation parameters have been computed from Arrhenius and Eyring plots.",

author = "Yashoda, \{M. P.\} and Padmalatha and Sherigara, \{B. S.\} and Nayak, \{P. V.\}",

year = "1999",

month = feb,

language = "English",

volume = "38",

pages = "176--179",

journal = "Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry",

issn = "0376-4710",

publisher = "Scientific Publishers of India",

number = "2",

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TY - JOUR

T1 - Titanium (III) reduction of dimethylglyoxime

T2 - Electrochemical and kinetic studies

AU - Yashoda, M. P.

AU - Padmalatha,

AU - Sherigara, B. S.

AU - Nayak, P. V.

PY - 1999/2

Y1 - 1999/2

N2 - Titanium (III) mediated electroreduction of dimethyl glyoxime has been carried out in aqueous sulphuric acid medium and the reduction product has been isolated and characterised. The kinetic investigations have been carried out under stoichiometric and non-stoichiometric conditions at 306K. It has been found that the reaction follows overall second order kinetics, first order each in [Ti(III)] and [DMG] and fractional order in sulphuric acid. The effect of varying concentrations of Ti(III), DMG, H2SO4, ionic strength, and solvent composition has been studied. Effect of temperature has also been studied and activation parameters have been computed from Arrhenius and Eyring plots.

AB - Titanium (III) mediated electroreduction of dimethyl glyoxime has been carried out in aqueous sulphuric acid medium and the reduction product has been isolated and characterised. The kinetic investigations have been carried out under stoichiometric and non-stoichiometric conditions at 306K. It has been found that the reaction follows overall second order kinetics, first order each in [Ti(III)] and [DMG] and fractional order in sulphuric acid. The effect of varying concentrations of Ti(III), DMG, H2SO4, ionic strength, and solvent composition has been studied. Effect of temperature has also been studied and activation parameters have been computed from Arrhenius and Eyring plots.

UR - https://www.scopus.com/pages/publications/0033041810

UR - https://www.scopus.com/pages/publications/0033041810#tab=citedBy

M3 - Article

AN - SCOPUS:0033041810

SN - 0376-4710

VL - 38

SP - 176

EP - 179

JO - Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry

JF - Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry

IS - 2

ER -

Titanium (III) reduction of dimethylglyoxime: Electrochemical and kinetic studies

Abstract

All Science Journal Classification (ASJC) codes

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